甲基7-(5-氧代-1-环戊烯-1-基)庚酸酯合成路线 （共 105 条）
反应条件
1: 60 percent / di-tert-butyl peroxide (DTBP) / 1.75 h / 135 - 140 °C
2: 1.) 30percent (w/w) H2O2, 55percent H2SO4; 2.) polyphosphoric acid (PPA) / 1.) a.) 60 deg C, 45 min; b.) RT, 2 h; 2.) 85 deg C, 10 min
View Scheme
参考文献
Ogibin; Starostin; Aleksandrov; Pivnitsky; Nikishin
Synthesis, 1994 , # 9 p. 901 - 903
反应条件
1: 1.) 30percent (w/w) H2O2, 55percent H2SO4; 2.) polyphosphoric acid (PPA) / 1.) a.) 60 deg C, 45 min; b.) RT, 2 h; 2.) 85 deg C, 10 min
View Scheme
参考文献
Ogibin; Starostin; Aleksandrov; Pivnitsky; Nikishin
Synthesis, 1994 , # 9 p. 901 - 903
参考文献
Gokhale; Dalavoy; Prakasa Rao; et al.
Synthesis, 1974 , vol. No. 10, p. 718 - 719
反应条件
1: 60 percent / di-tert-butyl peroxide (DTBP) / 1.75 h / 135 - 140 °C
2: 1.) 30percent (w/w) H2O2, 55percent H2SO4, AcOH; 2.) polyphosphoric acid (PPA) / 1.) a.) 60 deg C below, 45 min; b.) RT, 2 h; 2.) 85 deg C, 10 min
View Scheme
参考文献
Ogibin; Starostin; Aleksandrov; Pivnitsky; Nikishin
Synthesis, 1994 , # 9 p. 901 - 903
反应条件
1: ZnCl2
2: (i) HgCl2, CdCO3, (ii) K2CO3, MeOH
View Scheme
参考文献
Ide,J. et al.
Bulletin of the Chemical Society of Japan, 1978 , vol. 51, # 3 p. 939 - 940
反应条件
hydrogenchloride; PPA
1.) 100 deg C, 1 h, 2.) room temp., 1 d; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Dalcanale, Enrico; Foa, Marco
Synthesis, 1986 , # 6 p. 492 - 494
反应条件
hydrogenchloride; methanol
1.) 100 deg C, 1 h, 2.) room temperature, 1 d; Yield given. Yields of byproduct given;
参考文献
Bonsignore, S.; Dalcanale, E.; Martinengo, T.
Synthetic Communications, 1988 , vol. 18, # 18 p. 2241 - 2250
反应条件
dicobalt octacarbonyl
1) light petroleum, r.t., 2 h, 2) toluene, 160 deg C, 15 atm, 7 h; Yield given. Multistep reaction;
参考文献
Newton, Roger F.; Pauson, Peter L.; Taylor, Ronald G.
Journal of Chemical Research, Miniprint, 1980 , # 9 p. 3501 - 3522
反应条件
2,3,5-trimethyl-pyridine; copper(ll) bromide
1) ethyl acetate, chloroform, 20 deg C, 200 mm Hg, 5-6 h, 2) 60-70 deg C, o.5-1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Lapitskaya, M. A.; Manukina, T. A.; Nozdracheva, A. T.; Sheimina, L. G.; Pivnitskii, K. K.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 261 - 265
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 2 p. 294 - 299
反应条件
(i) HgCl2, CdCO3, (ii) K2CO3, MeOH; Multistep reaction;
参考文献
Ide,J. et al.
Bulletin of the Chemical Society of Japan, 1978 , vol. 51, # 3 p. 939 - 940
