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乙二醇
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63148-62-9
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二甲基亚砜
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471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
3542-14-1
合成路线
（共 47 条）
947-91-1
联苯乙醛
→
反应条件
3542-14-1
反应条件
1: Methyltriphenylphosphonium bromide With n-butyllithium in tetrahydrofuran T=-78 - 20°C; 2.25 h; 2: 2,2-diphenylacetaldehyde in tetrahydrofuran T=-78 - 20°C; 24 h;
参考文献
WAYNE STATE UNIVERSITY
Patent: WO2005/105075 A1, 2005 ;
Location in patent: Page/Page column 39; Sheet 6 ;
WO 2005/105075 A1
947-91-1
联苯乙醛
+
1779-49-3
甲基三苯基溴化膦
→
反应条件
3542-14-1
反应条件
1: Methyltriphenylphosphonium bromide With n-butyllithium in tetrahydrofuran T=20°C; 2 h; 2: 2,2-diphenylacetaldehyde in tetrahydrofuran T=20°C; 24 h;
参考文献
Zhang, Shijun; Zhen, Juan; Reith, Maarten E. A.; Dutta, Aloke K.
Journal of Medicinal Chemistry, 2005 , vol. 48, # 15 p. 4962 - 4971
100-58-3
溴化苯基镁
+
4392-24-9
肉桂基溴
→
反应条件
3542-14-1
+
3412-44-0
反应条件
n-butyllithium; (4R),(5R)-N,N'-dimethyl-4,5-diphenyl-4,5-dihydroimidazolinium iodide; copper(l) chloride in hexane; dichloromethane T=25°C; 1 h; Inert atmosphere; Overall yield = 99 percentSpectr.; regioselective reaction;
参考文献
Ando, Shin; Matsunaga, Hirofumi; Ishizuka, Tadao
Tetrahedron, 2013 , vol. 69, # 6 p. 1687 - 1693
1826-67-1
乙烯基溴化镁
+
776-74-9
二苯基溴甲烷
→
反应条件
3542-14-1
反应条件
dichloro bis(acetonitrile) palladium(II); 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in tetrahydrofuran; acetonitrile T=20°C; Kumada-Corriu reaction; 14 h; Inert atmosphere;
参考文献
Lopez-Perez, Ana; Adrio, Javier; Carretero, Juan C.
Organic Letters, 2009 , vol. 11, # 23 p. 5514 - 5517
4407-36-7
3-苯基丙-2-烯-1-醇
+
98-80-6
苯硼酸
→
反应条件
3542-14-1
+
3412-44-0
反应条件
triphenylphosphine; bis(η3-allyl-μ-chloropalladium(II)) in water T=110°C; 4 h; Title compound not separated from byproducts;
参考文献
Manabe, Kei; Nakada, Kenji; Aoyama, Naohiro; Kobayashi, Shu
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 11-13 p. 1499 - 1503
4393-06-0
1-苯基-2-丙烯-1-醇
+
98-80-6
苯硼酸
→
反应条件
3542-14-1
+
3412-44-0
反应条件
triphenylphosphine; bis(η3-allyl-μ-chloropalladium(II)) in water T=110°C; 4 h; Title compound not separated from byproducts;
参考文献
Manabe, Kei; Nakada, Kenji; Aoyama, Naohiro; Kobayashi, Shu
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 11-13 p. 1499 - 1503
24808-73-9
+
98-80-6
苯硼酸
→
反应条件
3542-14-1
+
3412-44-0
反应条件
triphenylphosphine; bis(η3-allyl-μ-chloropalladium(II)) in water T=110°C; 4 h; Title compound not separated from byproducts;
参考文献
Manabe, Kei; Nakada, Kenji; Aoyama, Naohiro; Kobayashi, Shu
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 11-13 p. 1499 - 1503
21087-29-6
肉桂基氯
→
反应条件
3542-14-1
+
3412-44-0
+
58463-02-8
+
74120-63-1
反应条件
phenyl-magnesium bromide in diethyl ether T=30°C; 1 h;
参考文献
Muraoka, Kiyoshige; Nojima, Masatomo; Kusabayashi, Shigekazu; Nagase, Shigeru
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 761 - 768
300-57-2
烯丙基苯
+
108-86-1
溴代苯
→
反应条件
3542-14-1
反应条件
palladium diacetate; lithium hexamethyldisilazane; tri-cyclo-hexyl-phosphine T=80°C; 24 h; Inert atmosphere; TemperatureReagent/catalystSolvent; chemoselective reaction;
参考文献
Hussain, Nusrah; Frensch, Gustavo; Zhang, Jiadi; Walsh, Patrick J.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 14 p. 3693 - 3697
Angew. Chem., 2014 , vol. 126, # 14 p. 3767 - 3771,5
591-51-5
苯基锂
+
4392-24-9
肉桂基溴
→
反应条件
3542-14-1
+
3412-44-0
反应条件
copper(l) iodide; boron trifluoride diethyl etherate in diethyl ether
参考文献
Yamamoto, Yoshinori; Yamamoto, Shinichi; Yatagai, Hidetaka; Maruyama, Kazuhiro
Journal of the American Chemical Society, 1980 , vol. 102, # 7 p. 2318 - 2325
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