2-甲基-6-次甲基-2,7-辛二烯-4-醇合成路线 （共 20 条）
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran Ambient temperature;
参考文献
Mori; Takikawa
Tetrahedron, 1991 , vol. 47, # 12-13 p. 2163 - 2168
反应条件
titanium(IV) isopropylate; (i-C3H7)SB(C2H5)2; (R)-2,2'-dihydroxy-1,1'-binaphthyl in various solvent(s) T=-20°C; 5 h; Title compound not separated from byproducts.;
参考文献
European Journal of Organic Chemistry, , # 6 p. 1143 - 1148
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=0°C; 1 h; Yield given;
参考文献
Synthetic Communications, , vol. 27, # 6 p. 1029 - 1036
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Tetrahedron, , vol. 35, p. 933 - 940
反应条件
1: 71 percent / imidazole / dimethylformamide / Ambient temperature 2: (i-Bu)2AlH / toluene / -78 °C 3: 1,2-dimethoxy-ethane / -15 °C 4: 92 percent / (n-Bu)4NF / tetrahydrofuran / Ambient temperature View Scheme
参考文献
Tetrahedron, , vol. 47, # 12-13 p. 2163 - 2168
反应条件
1: 1,2-dimethoxy-ethane / -15 °C 2: 92 percent / (n-Bu)4NF / tetrahydrofuran / Ambient temperature View Scheme
参考文献
Tetrahedron, , vol. 47, # 12-13 p. 2163 - 2168
反应条件
1: (i-Bu)2AlH / toluene / -78 °C 2: 1,2-dimethoxy-ethane / -15 °C 3: 92 percent / (n-Bu)4NF / tetrahydrofuran / Ambient temperature View Scheme
参考文献
Tetrahedron, , vol. 47, # 12-13 p. 2163 - 2168
反应条件
1: (i) Pb(OAc)4, (ii) (saponification), (iii) MnO2 2: (i) NaH, THF, (ii) aq. H3BO3 3: LiAlH4 / diethyl ether 4: 550 °C / 0.01 Torr View Scheme
参考文献
Helvetica Chimica Acta, , vol. 60, p. 1496 - 1500
反应条件
1: (i) NaH, THF, (ii) aq. H3BO3 2: LiAlH4 / diethyl ether 3: 550 °C / 0.01 Torr View Scheme
参考文献
Helvetica Chimica Acta, , vol. 60, p. 1496 - 1500
反应条件
potassium tert-butylate; tert-butyl alcohol 1 h; Inert atmosphereReflux;
参考文献
Kovalenko; Matyushenkov
Russian Journal of Organic Chemistry, 2012 , vol. 48, # 9 p. 1168 - 1172
Zh. Org. Khim., 2012 , vol. 48, # 9 p. 1172 - 1175,4
