in diethyl ether under Ar; from a 1:3 stoich. react. of SbCl3 and Me2NLi in Et2O; according to A. Kiennemann et al., J. Organomet. Chem., 1972, 35, 143; purifn. by distn.;
参考文献
Edge, Ruth; Less, Robert J.; Naseri, Vesal; McInnes, Eric J. L.; Mulvey, Robert E.; Wright, Dominic S.
Dalton Transactions, 2008 , # 45 p. 6454 - 6460
in diethyl ether byproducts: LiCl; reaction mixture cooled to -50°C; stirred for 2 h at room temp.;; filtered; ether was removed under vacuum; distilled at 50°C at 0.2 Torr;;
参考文献
Wan, Yanjian; Verkade, John G.
Inorganic Chemistry, 1993 , vol. 32, p. 79 - 81
in tetrahydrofuran byproducts: LiOSi(CH3)3; a suspn. of germatrane in THF was treated with an excess of (Me2)NLi inn-hexane at room temp. for 4 h; evap., filtered;
参考文献
Karlov, Sergey S.; Shutov, Pavel L.; Akhmedov, Novruz G.; Seip, Markus A.; Lorberth, Joerg; Zaitseva, Galina S.
Journal of Organometallic Chemistry, 2000 , vol. 598, # 2 p. 387 - 394
in diethyl ether; benzene byproducts: LiCl; addn. of SnCl4 in benzene under exclusion of air and moisture to a soln. of LiN(CH3)2 in ether; refluxion for 4 h; filtration;; distn. of the solvent; distn. of the residue in high vac.;;
参考文献
Jones, K.; Lappert, M. F.
Journal of the Chemical Society, 1965 , p. 1944 - 1951
