2-溴-1,1-二氟乙烯合成路线 （共 16 条）
反应条件
cobalt(III) fluoride T=35°C;
参考文献
Journal of Organic Chemistry, , vol. 28, p. 494 - 497
反应条件
(i) nBuLi, Et2O, (ii) H2O; Multistep reaction;
参考文献
Drakesmith,F.G. et al.
Journal of Organic Chemistry, 1968 , vol. 33, # 1 p. 286 - 291
反应条件
1: 2-bromo-1,1-difluoroethylene With zinc(II) chloride; lithium diisopropyl amide in tetrahydrofuran
T=15°C; 2 h;
2: iodobenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
参考文献
Anilkumar; Burton, Donald J.
Journal of Fluorine Chemistry, 2004 , vol. 125, # 4 p. 561 - 566
反应条件
tetrakis(triphenylphosphine) palladium(0); chloro-trimethyl-silane; diiodomethane; zinc
1.) THF, 60-90 deg C, 30 min, 2.) THF, 60 deg C, 4 h; Yield given. Multistep reaction. Further byproducts given;
参考文献
Nguyen, Ba V.; Burton, Donald J.
Journal of Organic Chemistry, 1997 , vol. 62, # 22 p. 7758 - 7764
参考文献
Sullivan,R. et al.
Journal of Organic Chemistry, 1964 , vol. 29, p. 3664 - 3668
反应条件
tetrakis(triphenylphosphine) palladium(0); chloro-trimethyl-silane; diiodomethane; zinc
1.) THF, 60-90 deg C, 30 min, 2.) THF, 60 deg C, 4 h; Yield given. Multistep reaction. Further byproducts given;
参考文献
Nguyen, Ba V.; Burton, Donald J.
Journal of Organic Chemistry, 1997 , vol. 62, # 22 p. 7758 - 7764
