(8S,9S,10R,11S,13S,14S)-11,17-二羟基-10,13-二甲基-3-氧代-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊二烯并[a]菲-17-羧酸合成路线 （共 6 条）
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3597-45-3(8S,9S,10R,11S,13S,14S)-11,17-二羟基-10,13-二甲基-3-氧代-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊二烯并[a]菲-17-羧酸
反应条件
in tetrahydrofuran; methanol; water
参考文献
BODOR, Nicholas S.
Patent: EP334853 A1, 1989 ;
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3597-45-3(8S,9S,10R,11S,13S,14S)-11,17-二羟基-10,13-二甲基-3-氧代-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊二烯并[a]菲-17-羧酸
反应条件
potassium hydroxide in ethanol 1.66667 h; Ambient temperaturein presence and absence of O2, further reagent: NaOMe; Mechanism;
参考文献
Simons, S. Stoney; Merchlinsky, Michael J.; Johnson, David F.
Steroids, 1981 , vol. 37, # 3 p. 281 - 290
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3597-45-3(8S,9S,10R,11S,13S,14S)-11,17-二羟基-10,13-二甲基-3-氧代-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊二烯并[a]菲-17-羧酸
参考文献
Mason; Hoehn; Kendall
Journal of Biological Chemistry, 1938 , vol. 124, p. 459,465
Full Text Show Details
v.Euw; Reichstein
Helvetica Chimica Acta, 1942 , vol. 25, p. 988,1002
Helvetica Chimica Acta, 1947 , vol. 30, p. 205,206,210
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3597-45-3(8S,9S,10R,11S,13S,14S)-11,17-二羟基-10,13-二甲基-3-氧代-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊二烯并[a]菲-17-羧酸
参考文献
Mason; Hoehn; Kendall
Journal of Biological Chemistry, 1938 , vol. 124, p. 459,465
Full Text Show Details
v.Euw; Reichstein
Helvetica Chimica Acta, 1942 , vol. 25, p. 988,1002
Helvetica Chimica Acta, 1947 , vol. 30, p. 205,206,210
3597-45-3(8S,9S,10R,11S,13S,14S)-11,17-二羟基-10,13-二甲基-3-氧代-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊二烯并[a]菲-17-羧酸
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反应条件
chromium(VI) oxide; acetic acid
参考文献
Mason; Hoehn; Kendall
Journal of Biological Chemistry, 1938 , vol. 124, p. 459,465
3597-45-3(8S,9S,10R,11S,13S,14S)-11,17-二羟基-10,13-二甲基-3-氧代-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊二烯并[a]菲-17-羧酸+
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参考文献
Mason; Hoehn; Kendall
Journal of Biological Chemistry, 1938 , vol. 124, p. 459,465
