17-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇合成路线 （共 19 条）
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3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
参考文献
Ruzicka; Hofmann
Helvetica Chimica Acta, 1937 , vol. 20, p. 1280
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3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇+
反应条件
anfangs unter starker Kuehlung;
参考文献
Reichstein; Meystre
Helvetica Chimica Acta, 1939 , vol. 22, p. 728,737
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3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
参考文献
Claude
Patent: FR809819 , 1936 ;
3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
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反应条件
1: mercury bis-<toluene-sulfonyl-(4)-amide>; ethanol / und Einleiten von H2S in das Reakionsgemisch View Scheme
参考文献
Helvetica Chimica Acta, , vol. 22, p. 1188
3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
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反应条件
Al tri-t-BuO-; acetone; benzene
参考文献
Inhoffen et al.
Chemische Berichte, 1938 , vol. 71, p. 1024,1030
Full Text Show Details
Schering Corp.
Patent: US2323911 , 1937 ;
3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
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反应条件
1: mercury bis-<toluene-sulfonyl-(4)-amide>; ethanol / und Einleiten von H2S in das Reakionsgemisch 2: pyridine View Scheme
参考文献
Goldberg; Aeschbacher
Helvetica Chimica Acta, 1939 , vol. 22, p. 1188
3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
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反应条件
ethanol; mercury(II) acetamide und Einleiten von H2S in das Reakionsgemisch;
参考文献
Goldberg; Aeschbacher
Helvetica Chimica Acta, 1939 , vol. 22, p. 1188
Full Text Show Details
Goldberg; Aeschbacher; Hardegger
Helvetica Chimica Acta, 1943 , vol. 26, p. 680,685
3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
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反应条件
anschliessendes Einleiten von H2S;
参考文献
Shoppee; Prins
Helvetica Chimica Acta, 1943 , vol. 26, p. 1004,1013
Full Text Show Details
Goldberg; Aeschbacher
Helvetica Chimica Acta, 1939 , vol. 22, p. 1188
3604-60-217-乙炔基-10,13-二甲基-1,2,3,4,7,8,9,11,12,14,15,16-十二氢环戊烯并[a]菲-3,17-二醇
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反应条件
1: Hydrogenation 2: acetone; aluminium tert-butylate; benzene View Scheme
参考文献
Ruzicka et al.
Helvetica Chimica Acta, 1938 , vol. 21, p. 583,586
Helvetica Chimica Acta, 1933 , vol. 16, p. 169,177
