2-氨基-4‘-甲基苯甲酮合成路线 （共 42 条）
反应条件
1: With silver hexafluoroantimonate; {RuCl2(1-methyl-4-(1-methylethyl)benzene)}2; copper (II) acetate monohydrate in 1,2-dichloro-ethane T=100°C; 24 h; Inert atmosphereSchlenk technique; 2: With sulfuric acid T=0 - 20°C; 2 h; Inert atmosphereSchlenk technique; 3: With sodium hydrogencarbonate Inert atmosphereSchlenk technique;
参考文献
Chemical Communications, , vol. 49, # 45 p. 5225 - 5227
反应条件
1: concentrated sulfuric acid 2: tin dichloride; alcoholic hydrochloric acid View Scheme
参考文献
Chemische Berichte, , vol. 41, p. 1845
反应条件
potassium carbonate T=80°C; Suzuki Coupling; P=760.051 Torr; 12 h; Green chemistry;
参考文献
ChemCatChem, , vol. 5, # 1 p. 349 - 354
反应条件
aluminium trichloride T=5 - 8°C; 0.75 h;
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 22, # 11 p. 1132 - 1138
反应条件
1: 1.) magnesium / 1.) ether, 2.) ice-bath, 4 h 2: 1.) conc. HCl, sodium nitrite, 2.) sodium azide, sodium acetate / 1.) acetic acid, water, below 5 deg C 3: 94 percent / various solvent(s) / 3 h / Heating 4: 8 percent / various solvent(s) / 6 h / Heating View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2077 - 2087
反应条件
1: 1.) conc. HCl, sodium nitrite, 2.) sodium azide, sodium acetate / 1.) acetic acid, water, below 5 deg C 2: 94 percent / various solvent(s) / 3 h / Heating 3: 8 percent / various solvent(s) / 6 h / Heating View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2077 - 2087
反应条件
1: tetrahydrofuran; diethyl ether 2: CuCl2*H2O; potassium carbonate / N,N-dimethyl-formamide / 24 h / 60 °C View Scheme
参考文献
Chemical Communications, , vol. 47, # 33 p. 9513 - 9515
反应条件
.LAMBDA.-(+)-tris(acetylacetonato)chromium(III) in various solvent(s) 4 h; Heatingfurther metal catalysts; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2077 - 2087
反应条件
(i) PCl5, (ii) AlCl3, (iii) H2SO4; Multistep reaction;
参考文献
Journal of the American Chemical Society, , vol. 94, p. 4952 - 4958
参考文献
Bolton, Roger; Mguni, Raphael S.; Williams, Gareth H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 405 - 408
