4-羟基-2,3,6-三甲基乙酸苯酯合成路线 （共 22 条）
反应条件
toluene-4-sulfonic acid in Ethylene carbonate; n-heptane T=100°C; 0.0833333 h;
参考文献
DSM IP ASSETS B.V.
Patent: WO2004/46126 A1, 2004 ;
Location in patent: Page 13-15 ;
反应条件
ammonium hydroxide; triethylamine in methanol
参考文献
Hoechst Marion Roussel, Inc.
Patent: US6114572 A1, 2000 ;
反应条件
Lipozyme 435 in tert-butyl methyl ether
T=30°C; 6 h; Enzymatic reaction; regioselective reaction;
参考文献
Wei, Chun; Fu, Xian-Feng; Wang, Zhao; Yu, Xin-Jun; Zhang, Yin-Jun; Zheng, Jian-Yong
Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 106, p. 90 - 94
参考文献
Kuraray Co., Ltd.
Patent: US6130341 A1, 2000 ;
反应条件
Lipozyme RM IM in hexane; tert-butyl methyl ether
T=50°C; Enzymatic reaction; Kinetics; Reagent/catalystSolventConcentration; regioselective reaction;
参考文献
Wei, Chun; Fu, Xian-Feng; Wang, Zhao; Yu, Xin-Jun; Zhang, Yin-Jun; Zheng, Jian-Yong
Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 106, p. 90 - 94
反应条件
peracetic acid
T=50°C; 0.25 h; Product distributionKineticsThermodynamic data;
参考文献
Kharchuk, V. G.; Kolenko, I. P.; Petrov, L. A.; Gus'kova, L. M.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 11 p. 2071 - 2078
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 11 p. 2306 - 2315
反应条件
sulfuric acid
T=50°C; 0.5 h; effect of catalysts; MechanismThermodynamic data;
参考文献
Kharchuk, V. G.; Kolenko, I. P.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 4 p. 923 - 930,819 - 826
反应条件
peracetic acid
T=50°C; 0.25 h; Product distributionKineticsThermodynamic data;
参考文献
Kharchuk, V. G.; Kolenko, I. P.; Petrov, L. A.; Gus'kova, L. M.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 11 p. 2071 - 2078
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 11 p. 2306 - 2315
参考文献
Merck,E.
Patent: DE736797 , 1940 ;
DRP/DRBP Org.Chem.
Full Text Show Details
Merck and Co. Inc.
Patent: US2359311 , 1941 ;
反应条件
(i) Py, (ii) aq. NH3, MeOH; Multistep reaction;
参考文献
Weichet,J. et al.
Collection of Czechoslovak Chemical Communications, 1966 , vol. 31, p. 4598 - 4609
