5-甲基-2,3-二(苯基)-1H-吲哚合成路线 （共 32 条）
反应条件
1: potassium acetate 2: chromium (VI)-oxide; acetic acid / und Erwaermen des Reaktionsprodukts mit aethanol.Kalilauge 3: aqueous H2SO4; NaNO2 / anschliessendes Erhitzen View Scheme
参考文献
Ritchie
Journal and Proceedings of the Royal Society of New South Wales, 1946 , vol. 80, p. 33,40
反应条件
lithium hydroxide hydrate; C24H23N3O3PdS in N,N-dimethyl-formamide
T=130°C; Larock Annulation; 20 h; regioselective reaction;
参考文献
Srinivas, Keesara; Saiprathima, Parvathaneni; Balaswamy, Kodicherla; Ra, Mandapati Mohan
Journal of Organometallic Chemistry, 2013 , vol. 741-742, # 1 p. 162 - 167
反应条件
1,1'-bis-(di-tert-butylphosphino)ferrocene; potassium carbonate; palladium diacetate in 1-methyl-pyrrolidin-2-one
T=130°C;
参考文献
Shen, Ming; Li, Guisheng; Lu, Bruce Z.; Hossain, Azad; Roschangar, Frank; Farina, Vittorio; Senanayake, Chris H.
Organic Letters, 2004 , vol. 6, # 22 p. 4129 - 4132
反应条件
1: With Cp*Rh(H2O)3(OTf)2; oxygen; acetic anhydride in 1,1-dimethylpropan-1-ol
T=40°C; P=760.051 Torr; 24 h; Inert atmosphereSchlenk technique;
2: With sodium hydroxide in methanol; 1,1-dimethylpropan-1-ol
T=20°C; 1 h;
参考文献
Zhang, Guoying; Yu, Hui; Qin, Guiping; Huang, Hanmin
Chemical Communications, 2014 , vol. 50, # 33 p. 4331 - 4334
反应条件
potassium carbonate; palladium diacetate in N,N-dimethyl-formamide
T=130°C; 30 h;
参考文献
Cui, Xin; Li, Juan; Fu, Yao; Liu, Lei; Guo, Qing-Xiang
Tetrahedron Letters, 2008 , vol. 49, # 21 p. 3458 - 3462
反应条件
carbon monoxide; [(1,10-phenanthroline)Pd](tetrafluoroborate)2 in ethylene glycol dimethyl ether
T=170°C; P=45003.6 Torr; 10 h;
参考文献
Ragaini, Fabio; Rapetti, Andrea; Visentin, Elena; Monzani, Michela; Caselli, Alessandro; Cenini, Sergio
Journal of Organic Chemistry, 2006 , vol. 71, # 10 p. 3748 - 3753
反应条件
[(η5-C5Me5)2Rh2(μ-Cl)2Cl2]; potassium acetate; isobutyraldehyde in methanol
T=80°C; 12 h; Inert atmosphereSealed tube; regioselective reaction;
参考文献
Zheng, Liyao; Hua, Ruimao
Chemistry - A European Journal, 2014 , vol. 20, # 8 p. 2352 - 2356
反应条件
phosphorus trichoride in dichloromethane
0.25 h; Ambient temperature;
参考文献
Baccolini, Graziano; Marotta, Emanuela
Tetrahedron, 1985 , vol. 41, # 20 p. 4615 - 4620
反应条件
[{(η5-C5Me5)RhCl}2(μ-Cl)2]; caesium acetate; acetic acid in 1,2-dichloro-ethane
T=70°C; 16 h; Inert atmosphere;
参考文献
Zhao, Dongbing; Shi, Zhuangzhi; Glorius, Frank
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12426 - 12429
Angew. Chem., 2013 , vol. 125, # 47 p. 12652 - 12656,4
反应条件
palladium on activated charcoal
T=370°C;
参考文献
Allen; VanAllan
Journal of the American Chemical Society, 1951 , vol. 73, p. 5850,5853
