4-甲基戊-4-烯-2-酮合成路线 （共 26 条）
反应条件
boron trifluoride diethyl etherate
T=0 - 25°C; nachfolgendes Destillieren;
参考文献
Eastman Kodak Co.
Patent: US2450133 , 1947 ;
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Eastman Kodak Co.
Patent: US2462357 , 1948 ;
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Eastman Kodak Co.
Patent: US2450134 , 1947 ;
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Eastman Kodak Co.
Patent: US2450118 , 1947 ;
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Eastman Kodak Co.
Patent: US2450116 , 1947 ;
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Eastman Kodak Co.
Patent: US2450117 , 1947 ;
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Hagemeyer
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 769
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Eastman Kodak Co.
Patent: US2450132 , 1947 ;
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Eastman Kodak Co.
Patent: US2450131 , 1947 ;
反应条件
in dichloromethane
(i) SbCl5, (ii) /BRN= 773645/, dicyclohexyl-ethyl-amine; Multistep reaction;
参考文献
Hoffmann,H.M.R.; Tsushima,T.
Journal of the American Chemical Society, 1977 , vol. 99, p. 6008 - 6011
反应条件
in dichloromethane
-70 deg C, then 20 deg C, 8 h;
参考文献
Tolstikov, G. A.; Valitov, F. Kh.; Kuchin, A. V.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 6 p. 1328 - 1334,1170 - 1175
反应条件
hydrogenchloride
1.) THF, -78 deg C, 1 h; Yield given. Multistep reaction;
参考文献
Dalpozzo, Renato; De Nino, Antonio; Bartoli, Giuseppe; Bosco, Marcella; Sambri, Letizia; Marcantoni, Enrico
Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3745 - 3747
反应条件
Zr-incorporated hydrotalcite
T=239.84°C; Aldol condensation; 2 h; Inert atmosphere;
参考文献
Liu, Yanxia; Sun, Kunpeng; Ma, Haowen; Xu, Xianlun; Wang, Xiaolai
Catalysis Communications, 2010 , vol. 11, # 10 p. 880 - 883
反应条件
magnesium oxide; isopropyl alcohol
T=250 - 350°C;
参考文献
Hall, Jessica F. B.; Bourne, Richard A.; Han, Xue; Earley, James H.; Poliakoff, Martyn; George, Michael W.
Green Chemistry, 2013 , vol. 15, # 1 p. 177 - 180
参考文献
Mikhailov,B.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1974 , vol. 44, # 11 p. 2466 - 2473,2425 - 2431
反应条件
1H-imidazole in N,N-dimethyl-formamide
Ambient temperatureIrradiationfurther with 4,4'-dimethoxybenzophenone; Product distributionMechanism;
参考文献
Wan, Calvin S. K.; Weedon, Alan C.
Journal of the Chemical Society, Chemical Communications, 1981 , # 23 p. 1235 - 1236
反应条件
low-valent titanium
T=200°C; var. temp.; Product distribution;
参考文献
Malinowski, M.; Dams, R.; Geise, H.J.
Bulletin des Societes Chimiques Belges, 1985 , vol. 94, # 2 p. 93 - 96
反应条件
low-valent titanium
T=300°C; 24 h; add of Ni, cyclopentadiene; var. temp.; Product distribution;
参考文献
Malinowski, Marek
Bulletin des Societes Chimiques Belges, 1985 , vol. 94, # 2 p. 97 - 100
