water in diethyl ether
byproducts: H2O; react. of B(OCH3)3 and RMgBr in ether at -75°C, hydrolysis, dehydration of dihydroxy borane (yield:70percent) on boiling with toluene (removal of H2O during course of react.);;
参考文献
McCusker et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 5179
View citing articles Show Details
Gmelin Handbook: B: B-Verb.13, 4.7.2.4, page 203 - 209
1: diethyl ether / Darst. Reinigung durch Ueberfuehrung in 1.2-Dibrom-nonan und Zerlegung des Dibromids mit verkupfertem Zink in 90prozentigem Aethanol in der Waerme
2: bromine / -12 - -5 °C
View Scheme
参考文献
Wilkinson
Journal of the Chemical Society, 1931 , p. 3061
dilithium tetrachlorocuprate in tetrahydrofuran
1) -60 to 25 deg C, 30 min, 2) 25 deg C, 30 min;
参考文献
Moiseenkov, Alexander M.; Czeskis, Boris A.; Ivanova, Natalya M.; Nefedov, Oleg M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , p. 2639 - 2649
