5-亚甲基螺[2.4]庚烷合成路线 （共 27 条）
反应条件
triphenylphosphine; (η3-allyl)(η5-Cp)Pd in toluene
T=118°C; P=30002.4 Torr; 20 h; var. of temp., pressure, conc., solvent, time; further catalyst: Pb(DBA)2; Product distributionMechanism;
参考文献
Binger, Paul; Weintz, Hans-Joachim
Chemische Berichte, 1984 , vol. 117, # 2 p. 654 - 665
反应条件
(.eta.2-methylenecyclopropane)bis(triphenylphosphine)nickel in benzene
T=60°C; 5 h; further reagent Ni(COD)2-PPh3; Further byproducts given. Yields of byproduct given;
参考文献
Furman, D. B.; Kudryashev, A. V.; Isaeva, L. S.; Peganova, T. A.; Ivanov, A. O.; et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1987 , vol. 36, # 6 p. 1132 - 1137
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987 , vol. 36, # 6 p. 1231 - 1236
反应条件
bis(1,5-cyclooctadiene)nickel (0)
1) r.t. to 70 deg C, 3 h, 2) 70 deg C to 25 deg C, 2 h; Yields of byproduct given;
参考文献
Binger, Paul; Brinkmann, Axel; Wedemann,Petra
Chemische Berichte, 1983 , vol. 116, # 8 p. 2920 - 2930
反应条件
bis(acetylacetonato) palladium; monoethoxy-diethylaluminum; tri-iso-propyl phosphine in benzene
T=100°C; P=3040 Torr; 2 h; var. Pd(0)-catal., var. allenes, var. times; Product distributionMechanism;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1980 , vol. 113, # 3 p. 1063 - 1071
反应条件
bis(1,5-cyclooctadiene)nickel (0)
T=40°C; 20 h; Yields of byproduct given;
参考文献
Binger, Paul; Brinkmann, Axel; Wedemann,Petra
Chemische Berichte, 1983 , vol. 116, # 8 p. 2920 - 2930
反应条件
acrylic acid methyl ester
1) Et2O, 32 deg C, 2 h, 2) toluene, 25 deg C, 4 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Binger, Paul; Doyle, Michael J.; Benn, Reinhard
Chemische Berichte, 1983 , vol. 116, # 1 p. 1 - 10
反应条件
lt;Nilt;P(NEt2)3gt;2gt;x (x gt;=1) in benzene
T=60°C; 7 h; other temperatures, other catalysts; Product distribution;
参考文献
Furman, D. B.; Munshieva, M. K.; Ivanov, A. O.; Belyankin, A. Yu.; Morozova, L. N.; et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 3.1 p. 465 - 469
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 3 p. 541 - 545
