in tetrahydrofuran T=20°C; Inert atmosphere; Equilibrium constant;

in tetrahydrofuran T=20°C; Inert atmosphere; Equilibrium constant;

in tetrahydrofuran (Ar); addn. of THF soln. of vinylmetalloderiv. to THF soln. of gold compd. at -20°C, stirring for 20 min, warming to room temp., stirringfor 1 h; Y. Shi, S.D. Ramgren and S.A. Blum, Organometallics, 2009, 28, 1275; evapn. in vac., addn. of benzene, filtration through celite, evapn. in vac., washing with pentane, drying, extn. (benzene), filtration, washing with pentane, drying in high vac., NMR and MS;

in tetrahydrofuran; diethyl ether under Ar, Schlenk techniques; suspn. of Au compd. in Et2O treated at -78°C with soln. of Mg compd. in THF (0.929:1.000 molar ratio); warmed to room temp. in 4 h, exposed to air for 10 min, filtered (MgSO4), evapd. (vac.), elem. anal.;

in tetrahydrofuran T=25°C; Inert atmosphere; Equilibrium constant;

in tetrahydrofuran T=25°C; Inert atmosphere; Equilibrium constant;

PdCl2(dppf) (1 molpercent) in acetonitrile byproducts: C6H4(CN)(CHCH2); 24 h;

PdCl2(dppf) (1 molpercent) in acetonitrile byproducts: C6H4(CH3)(CHCH2); 24 h;

PdCl2(dppf) (1 molpercent) in acetonitrile byproducts: C5H4N(CHCH2); 24 h;

PdCl2(dppf) (1 molpercent) in acetonitrile byproducts: C6H5CHCH2; 24 h;