(3E)-3,7-二甲基辛-1,3,6-三烯合成路线 （共 23 条）
反应条件
1: 82 percent
2: NaI / acetone / 1 h / 0 - 2 °C
3: triethylamine / hexane / 6 h / 25 °C / Irradiation
View Scheme
参考文献
Saplay, K. M.; Damodaran, N. P.; Dev, Sukh
Tetrahedron, 1983 , vol. 39, # 48 p. 2999 - 3004
反应条件
1: 86 percent
2: NaI / acetone / 1 h / 0 - 2 °C
3: triethylamine / hexane / 6 h / 25 °C / Irradiation
View Scheme
参考文献
Saplay, K. M.; Damodaran, N. P.; Dev, Sukh
Tetrahedron, 1983 , vol. 39, # 48 p. 2999 - 3004
反应条件
1: NaI / acetone / 1 h / 0 - 2 °C
2: triethylamine / hexane / 6 h / 25 °C / Irradiation
View Scheme
参考文献
Saplay, K. M.; Damodaran, N. P.; Dev, Sukh
Tetrahedron, 1983 , vol. 39, # 48 p. 2999 - 3004
反应条件
1: NaI / acetone / 1 h / 0 - 2 °C
2: triethylamine / hexane / 6 h / 25 °C / Irradiation
View Scheme
参考文献
Saplay, K. M.; Damodaran, N. P.; Dev, Sukh
Tetrahedron, 1983 , vol. 39, # 48 p. 2999 - 3004
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C
1.2: -78 - 20 °C
2.1: lithium aluminium tetrahydride / diethyl ether / 1 h / Inert atmosphere; Reflux
3.1: phosphorus tribromide / diethyl ether / 1 h / 0 °C / Inert atmosphere
4.1: dilithium tetrachlorocuprate / tetrahydrofuran; ethylene glycol dimethyl ether / 18.75 h / 0 - 20 °C
View Scheme
参考文献
Yildizhan, Selma; Schulz, Stefan
Synlett, 2011 , # 19 art. no. B08311ST, p. 2831 - 2833
反应条件
recombinant (+)-cadinene synthase from Gossypium arboreum; magnesium chloride; threo-1,4-dimercapto-2,3-butanediol in pentane
T=25°C; pH=7.5; 24 h; HEPES bufferEnzymatic reaction;
参考文献
Faraldos, Juan A.; Miller, David J.; Gonzalez, Veronica; Yoosuf-Aly, Zulfa; Cascon, Oscar; Li, Amang; Allemann, Rudolf K.
Journal of the American Chemical Society, 2012 , vol. 134, # 13 p. 5900 - 5908
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
other allylic acetates; var. solv.; also in presence var. bases and organometallic reagents; kinetic isotope effect; Product distributionMechanism;
参考文献
Keinan, Ehud; Kumar, Sandeep; Dangur, Vered; Vaya, Jacob
Journal of the American Chemical Society, 1994 , vol. 116, # 24 p. 11151 - 11152
反应条件
triethylamine in hexane
T=25°C; 6 h; Irradiation; Yield given. Yields of byproduct given;
参考文献
Saplay, K. M.; Damodaran, N. P.; Dev, Sukh
Tetrahedron, 1983 , vol. 39, # 48 p. 2999 - 3004
反应条件
triethylamine in hexane
T=25°C; 6 h; Irradiation; Product distribution;
参考文献
Saplay, K. M.; Damodaran, N. P.; Dev, Sukh
Tetrahedron, 1983 , vol. 39, # 48 p. 2999 - 3004
反应条件
tetrakis(triphenylphosphine) palladium(0); triethylamine in tetrahydrofuran
48 h; Ambient temperatureother dienylacetate, var. basic reagents; Product distribution;
参考文献
Matsushita, Hajime; Negishi, Ei-ichi
Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4161 - 4165
