potassium hydroxide; nitric acid in water 1000g KClO3, 1150 - 1250g I2, 30 - 40ml HCl (d 1.2), 2.5 - 3l H2O; in acidic soln. because of acceleration of reaction by formed Cl2; filtration of KIO3*HIO3, neutralization with KOH; mechanism discussed;;
参考文献
Gmelin Handbook: I: MVol.2, 121, page 506 - 508
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Putochin, N.
S.S.S.R. Nautschno-technitschesk. Upravlenie W.S.N.Ch. Nr. 181 (1927) 66
in water byproducts: Cl2; neutral soln.; slow reaction;;
参考文献
Guichard, M.
Bulletin de la Societe Chimique de France, 1909 , vol. 5, p. 724 - 724
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Gmelin Handbook: I: MVol.2, 121, page 506 - 508
in neat (no solvent) byproducts: O2; 1.5 mol KI/ mol KClO3; start at 350-400°C; violent reaction under formation of O2; mechanism discussed;; product mixture;;
参考文献
Lyden, R.
Finska kemistsamfundets Medd., 1927 , vol. 36, p. 126 - 126
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Gmelin Handbook: I: MVol.2, 121, page 506 - 508
