环戊基铁(II) 二羰基二聚体合成路线 （共 74 条）
反应条件
in tetrahydrofuran
N2-atmosphere; stirring of equimolar amts. (<=30°C, 19 h); solvent removal, chromy. (Al2O3 or Florisil); elem. anal.;
参考文献
Downs, R. L.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 91 - 104
反应条件
in benzene
react. of freshly distd. SO2Cl2 with Fe complex (mole ratio 1.7/1);;
参考文献
Manning, A. R.; McNally, Gerald; Davis, Reg; Rowland, Christopher C.
Journal of Organometallic Chemistry, 1983 , vol. 259, # 2 p. C15 - C16
反应条件
in methanol; benzene
A soln. of reagents in benzene/methanol, molar ratio 1:1, N2 atm.;; crystals were filtered off; washed with cold ether and dried; the filtrate was evapd. to dryness, recrystd. from toluene-pentane; elem. anal.;;
参考文献
Kumar, Rajesh; Manning, A. R.; Murray, Paul T.
Journal of Organometallic Chemistry, 1987 , vol. 323, p. 53 - 66
反应条件
in toluene
(N2); stirred in refluxed toluene for 3 h; evapd. (vac.); washed with hexane; extracted with THF; filtered through Celite; concentrated; layered with hexane; crystd. by solvent diffusion at -30°C over a period of 5 days; recrystd. from THF/hexane; elem. anal.;
参考文献
Clarkson, Lucy M.; Norman, Nicholas C.; Farrugia, Louis J.
Organometallics, 1991 , vol. 10, p. 1286 - 1292
反应条件
hydrogenchloride in acetonitrile
byproducts: HCl*2MeCN*2H2O; gas. HCl, in the absence of O2, room temp.;
参考文献
Callan, Brian; Manning, A.R.
Journal of Organometallic Chemistry, 1983 , vol. 252, # 3 p. C81 - C82
反应条件
in tetrahydrofuran
N2-atmosphere; stirring of Fe-complex soln. with 2 equiv. of CCl3SO2Cl (room temp., 12 h); solvent removal, extn. (CH2Cl2/C6H6=1:1), filtration, washing (petroleumether); elem. anal.;
参考文献
Downs, R. L.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 91 - 104
反应条件
chloroform in chloroform
Irradiation (UV/VIS); photolysis of (CpFe(CO)2)2 and PMe2Ph in CHCl3 soln.;; detected by IR-expt.;;
参考文献
Fergusson, Stuart B.; Sanderson, Laura J.; Shackleton, Thomas A.; Baird, Michael C.
Inorganica Chimica Acta, 1984 , vol. 83, p. L45 - L48
反应条件
in tetrahydrofuran
N2-atmosphere; stirring of equimolar amts. (<=30°C, 19 h); solvent removal, chromy. (Al2O3 or Florisil); elem. anal.;
参考文献
Downs, R. L.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 91 - 104
反应条件
in tetrachloromethane
Kinetics; byproducts: CCl3; sealing of a cell with Cp2Fe2(CO)4 and CCl4 against the atmosphere, shaking, rigorous storing in the dark at room temp. (30 d); detn. by IR spectroscopy;
参考文献
Castellani, Michael P.; Tyler, David R.
Organometallics, 1989 , vol. 8, p. 2113 - 2120
反应条件
in hexane
Irradiation (UV/VIS); N2 atmosphere; irradiation (366 nm, 20°C); not isolated; IR spectroscopy;
参考文献
Biddulph, Michael A.; Davis, Reg; Wilson, Fiona I. C.
Journal of Organometallic Chemistry, 1990 , vol. 387, # 3 p. 277 - 293
