4-甲氧基苯基-2-乙酰氨基-3,4,6-三-o-乙酰基-2-脱氧-beta-d-吡喃葡萄糖苷合成路线 （共 7 条）
反应条件
sodium hydroxide; t-Bu4NBr in dichloromethane
0.75 h; Ambient temperature;
参考文献
Roy, Rene; Tropper, Francois
Synthetic Communications, 1990 , vol. 20, # 14 p. 2097 - 2102
反应条件
boron trifluoride diethyl etherate in dichloromethane
T=20°C; Inert atmosphereCooling with ice;
参考文献
Fettke, Anja; Peikow, Dirk; Peter, Martin G.; Kleinpeter, Erich
Tetrahedron, 2009 , vol. 65, # 22 p. 4356 - 4366
反应条件
boron trifluoride diethyl etherate in dichloromethane
T=-30 - 20°C; 7 h;
参考文献
Liu, Qing-Chao; Guo, Tian-Tian; Zhao, Cong; Sun, Jing; Li, Wen-Hong
Helvetica Chimica Acta, 2014 , vol. 97, # 3 p. 361 - 368
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine
Heating;
参考文献
Yang, You; Yu, Biao
Tetrahedron Letters, 2007 , vol. 48, # 39 p. 7049 - 7052
反应条件
1: 1.) Et3N, 2.) Ac2O, pyridine / 1) 1,2-dichloroethane, 50-60 deg C, 2 h; 2) rt, 24 h
2: 87 percent / TMSOTf / 1,2-dichloro-ethane / 42 h
3: 1.) ethylenediamine, 2.) pyridine / 1) MeOH, 2 h; 2) CH2Cl2, 0 deg C, 18 h
View Scheme
参考文献
Lergenmueller, Matthias; Ito, Yukishige; Ogawa, Tomoya
Tetrahedron, 1998 , vol. 54, # 8 p. 1381 - 1394
反应条件
1: 87 percent / TMSOTf / 1,2-dichloro-ethane / 42 h
2: 1.) ethylenediamine, 2.) pyridine / 1) MeOH, 2 h; 2) CH2Cl2, 0 deg C, 18 h
View Scheme
参考文献
Lergenmueller, Matthias; Ito, Yukishige; Ogawa, Tomoya
Tetrahedron, 1998 , vol. 54, # 8 p. 1381 - 1394
反应条件
pyridine; ethylenediamine
1) MeOH, 2 h; 2) CH2Cl2, 0 deg C, 18 h; Yield given. Multistep reaction;
参考文献
Lergenmueller, Matthias; Ito, Yukishige; Ogawa, Tomoya
Tetrahedron, 1998 , vol. 54, # 8 p. 1381 - 1394
