Allen, Annette D.; Jansen, Michael P.; Koshy, Kalavelil M.; Mangru, Nevindra N.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 207 - 211
T=80.1°C; also with 80percent aq. EtOH at 54.3 - 85.1 deg C, with 80percent aq. EtOH in the presence of NaClO4, NaCl, NaOAc and NaN3 at 65.8 deg C, and with 100percent EtOH in the presence of NaOAc at 82.7 - 115.6 deg C; ΔH(excit.), ΔS(excit.); KineticsRate constantMechanism;
参考文献
Allen, Annette D.; Jansen, Michael P.; Koshy, Kalavelil M.; Mangru, Nevindra N.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 207 - 211
Allen, Annette D.; Jansen, Michael P.; Koshy, Kalavelil M.; Mangru, Nevindra N.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 207 - 211
Allen, Annette D.; Jansen, Michael P.; Koshy, Kalavelil M.; Mangru, Nevindra N.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 207 - 211
Allen, Annette D.; Jansen, Michael P.; Koshy, Kalavelil M.; Mangru, Nevindra N.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 207 - 211
Allen, Annette D.; Jansen, Michael P.; Koshy, Kalavelil M.; Mangru, Nevindra N.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 207 - 211
2,2'-azo-bisisobutyronitrile; oxygen in chlorobenzene T=95°C; 22 h; var. of temp., solvent, addition of cumene hydroperoxide, ΔEA; Product distributionThermodynamic dataKinetics;
1: 98 percent / AD-mix α / 2-methyl-propan-2-ol; H2O / 2 h / 20 °C 2: 96 percent / DMAP; Et3N / CH2Cl2 / 2 h / 20 °C 3: 96 percent / t-BuOK / acetonitrile / 12 h / 20 °C 4: 100 percent / TBAF / acetonitrile / 4 h / 20 °C 5: 78 percent / TEMPO; NaClO; NaClO2 / acetonitrile; aq. phosphate buffer / 4 h / 55 °C View Scheme
参考文献
Moreno-Dorado, F. Javier; Guerra, Francisco M.; Ortega, Maria J.; Zubia, Eva; Massanet, Guillermo M.
Tetrahedron Asymmetry, 2003 , vol. 14, # 4 p. 503 - 510
