1,1-二乙氧基-3-甲基丁烷合成路线 （共 18 条）
反应条件
oxalyl dichloride; potassium carbonate Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Menicagli, Rita; Malanga, Corrado; Guidi, Maurizio; Lardicci, Luciano
Tetrahedron, 1987 , vol. 43, # 1 p. 171 - 178
反应条件
1: 260 - 280 °C 2: BF3-Et2O 3: aq. TsOH View Scheme
参考文献
Breitmaier,E.; Gassenmann,S.
Chemische Berichte, 1971 , vol. 104, p. 665 - 667
反应条件
1: 260 - 280 °C 2: BF3-Et2O 3: aq. TsOH 4: aq. NH3 View Scheme
参考文献
Breitmaier,E.; Gassenmann,S.
Chemische Berichte, 1971 , vol. 104, p. 665 - 667
反应条件
aminosulfonic acid
T=25°C; 4 h;
参考文献
Gong, Weizhong; Wang, Bo; Gu, Yanglong; Yan, Liang; Yang, Liming; Suo, Jishuan
Synthetic Communications, 2004 , vol. 34, # 23 p. 4243 - 4247
反应条件
in hexane
T=35 - 40°C;
参考文献
Volkov, A. A.; Zlot-skii, S. S.; Kravets, E. Kh.; Rakhmankulov, D. L.
J. Gen. Chem. USSR (Engl. Transl.), 1986 , vol. 56, # 12 p. 2711 - 2714,2400 - 2402
参考文献
Tscheplanowa; Nemirowskii
Trudy Leningradsk.technol.Inst.LensovetaChem.Abstr., 1959 , # 58 p. 55
Trudy Leningradsk.technol.Inst.LensovetaChem.Abstr., 1960 , p. 34357
反应条件
potassium in N,N,N',N',N'',N''-hexamethylphosphoric triamide; diethyl ether
T=0°C;
参考文献
Cuvigny,T. et al.
Bulletin de la Societe Chimique de France, 1973 , p. 1174 - 1178
参考文献
McElvain; Clarke; Jones
Journal of the American Chemical Society, 1942 , vol. 64, p. 1968
反应条件
tri-isobutyl aluminium in toluene
T=40°C; 0.5 h; Yield given;
参考文献
Volkov, A. A.; Zlot-skii, S. S.; Kravets, E. Kh.; Rakhmankulov, D. L.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 8 p. 1605 - 1606
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 8 p. 1787 - 1788
反应条件
1: (i) Et2NH, Li, HMPT, benzene, (ii) /BRN= 635754/
2: K, HMPT / hexamethylphosphoric acid triamide; 2-methyl-propan-2-ol
View Scheme
参考文献
Larcheveque,M.; Cuvigny,T.
Tetrahedron Letters, 1975 , p. 3851 - 3854
