2-甲基-1-丙基溴化镁合成路线 （共 44 条）
参考文献
Normant
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1955 , vol. 240, p. 314
反应条件
N,N,N',N,-tetramethylethylenediamine; iron(III) chloride in tetrahydrofuran
T=0°C; 0.5 h;
参考文献
Guerinot, Amandine; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6521 - 6524
反应条件
in tetrahydrofuran; ethylene glycol dimethyl ether
T=0°C; 1 h;
参考文献
Lee, Jae In
Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 5 p. 1765 - 1768
反应条件
(trimethylsilyl)methylzinc iodide; anhydrous iron chloride; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran
T=0 - 30°C; Negishi coupling reaction; 25 h;
参考文献
Hatakeyama, Takuji; Nakagawa, Naohlsa; Nakamura, Masaharu
Organic Letters, 2009 , vol. 11, # 20 p. 4496 - 4499
反应条件
(trimethylsilyl)methylzinc iodide; anhydrous iron chloride; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran
T=0 - 30°C; Negishi coupling reaction; 19 h;
参考文献
Hatakeyama, Takuji; Nakagawa, Naohlsa; Nakamura, Masaharu
Organic Letters, 2009 , vol. 11, # 20 p. 4496 - 4499
反应条件
(trimethylsilyl)methylzinc iodide; anhydrous iron chloride; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran
T=0 - 40°C; Negishi coupling reaction; 25 h;
参考文献
Hatakeyama, Takuji; Nakagawa, Naohlsa; Nakamura, Masaharu
Organic Letters, 2009 , vol. 11, # 20 p. 4496 - 4499
反应条件
diethyl ether
beim Erwaermen des nach Hydrolyse erhaltenen Reaktionsprodukts unter vermindertem Druck;
参考文献
Daschkewitsch et al.
Naucn.Zap.Uzgorodsk.Univ.Chem.Abstr., 1957 , vol. 22, p. 81,104
Naucn.Zap.Uzgorodsk.Univ.Chem.Abstr., 1960 , p. 14100
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; CuBr*2LiBr; phosphorous acid trimethyl ester
1.) THF, -60 deg C, 15 min; 2.) 25 deg C, 16 h; Yield given. Multistep reaction;
参考文献
Kleijn; Westmijze; Meijer; Vermeer
Recueil des Travaux Chimiques des Pays Bas, 1981 , vol. 100, # 7-8 p. 249 - 255
反应条件
copper(I) bromide
1.) ether, THF, 30 deg C, 1 h, 2.) 8 h; Yield given. Multistep reaction;
参考文献
Scott, Fred; Nkwelo, Manning M.
Synthetic Communications, 1985 , vol. 15, # 12 p. 1051 - 1056
反应条件
1: 2-methyl-1-propenylmagnesium bromide With CuCN in diethyl ether
T=-30°C; 0.75 h;
2: N-morpholinecarbonyl chloride in diethyl ether
T=-30 - 20°C; 15 h;
参考文献
Lemoucheux, Laurent; Seitz, Thomas; Rouden, Jacques; Lasne, Marie-Claire
Organic Letters, 2004 , vol. 6, # 21 p. 3703 - 3706
