1: 2-chlorophenol With sodium hydroxide in water
T=0°C;
2: thiophosphoryl trichloride With tetrabutylammomium bromide in dichloromethane; water
T=0 - 20°C; 8 h;
in gas
Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;
参考文献
Critchley, Andrew D.J.; Howle, Chris R.; Mayhew, Chris A.; Tuckett, Richard P.
Chemical Physics, 2004 , vol. 303, # 1-2 p. 235 - 241
in neat (no solvent)
byproducts: KCl; on-line process; SPCl3 degassed in vac. line using liq. N2; SPCl3 vapor passed via vac. line over solid KI at 440°C (slow flow, 0.2 torr)into IR cell; detd. by IR spectra;
参考文献
Zidan, Mohammed D.; Allaf, Abdul W.
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2002 , vol. 58, # 8 p. 1577 - 1582
in neat (no solvent)
heating an excess of PSCl3 with PH4I in a sealing tube at 100 °C;;
参考文献
Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1896 , vol. 122, p. 1200 - 1202
Full Text Show Details
Gmelin Handbook: P: MVol.C, 260, page 594 - 596
in neat (no solvent)
react. of gaseous HI with PSCl3 cooled with a freezing-mixt. (NaCl-ice); absorption; heating at 0 °C, discoloration and evolution of H2S and HCl;;
参考文献
Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1896 , vol. 122, p. 1200 - 1202
Full Text Show Details
Gmelin Handbook: P: MVol.C, 260, page 594 - 596
Baudrimont, E.
Ann. Chim. Phys., 1864 , vol. 2, p. 5 - 67
Full Text Show Details
Chevrier
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1869 , vol. 68, p. 1174 - 1176
