(2-硝基苯基)环氧乙烷合成路线 （共 16 条）
参考文献
Chemische Berichte, , vol. 60, p. 451
Chemische Berichte, , vol. 61, p. 1112
反应条件
potassium hydroxide; 18-crown-6 ether in 1,4-dioxane 48 h; Ambient temperature; Yield given;
参考文献
Wierenga, Wendell; Harrison, Allen W.; Evans, Bruce R.; Chidester, Connie G.
Journal of Organic Chemistry, 1984 , vol. 49, # 3 p. 438 - 442
反应条件
sodium tetrahydroborate in 1,4-dioxane; water
1.) 2 h at 5 deg C; 2.) 30 min room temperature;
参考文献
Gravel, D.; Herbert, J.; Thoraval, D.
Canadian Journal of Chemistry, 1983 , vol. 61, p. 400 - 410
反应条件
sodium hydroxide in water
参考文献
Wierenga, Wendell; Harrison, Allen W.; Evans, Bruce R.; Chidester, Connie G.
Journal of Organic Chemistry, 1984 , vol. 49, # 3 p. 438 - 442
反应条件
3-chloro-benzenecarboperoxoic acid in dichloromethane
T=20°C;
参考文献
Xu, Wei; Xu, Jian-He; Pan, Jiang; Gu, Qing; Wu, Xin-Yan
Organic Letters, 2006 , vol. 8, # 8 p. 1737 - 1740
反应条件
potassium hydroxide; water in acetonitrile
T=60°C; 1 h; Further byproducts given. Yields of byproduct given;
参考文献
Borredon, Elisabeth; Delmas, Michel; Gaset, Antoine
Tetrahedron Letters, 1982 , vol. 23, # 50 p. 5283 - 5286
反应条件
1: potassium carbonate / dioxane; H2O / Heating
2: 3-chloroperoxybenzoic acid / CH2Cl2 / 20 °C
View Scheme
参考文献
Xu, Wei; Xu, Jian-He; Pan, Jiang; Gu, Qing; Wu, Xin-Yan
Organic Letters, 2006 , vol. 8, # 8 p. 1737 - 1740
反应条件
1: 68 percent / bromine / dioxane / 2 h
2: 88 percent / sodium borohydride / dioxane; H2O / 1.) 2 h at 5 deg C; 2.) 30 min room temperature
View Scheme
参考文献
Gravel, D.; Herbert, J.; Thoraval, D.
Canadian Journal of Chemistry, 1983 , vol. 61, p. 400 - 410
反应条件
triethylamine in methanol; diethyl ether
26 h; Ambient temperature;
参考文献
Hashimoto, Norio; Aoyama, Toyohiko; Shioiri, Takayuki
Heterocycles, 1981 , vol. 15, # 2 p. 975 - 979
反应条件
diethyl ether
T=-10°C;
参考文献
Arndt; Partale
Chemische Berichte, 1927 , vol. 60, p. 451
Full Text Show Details
Arndt; Eistert; Partale
Chemische Berichte, 1928 , vol. 61, p. 1112
