(三甲基硅基)乙酸乙酯合成路线 （共 118 条）
参考文献
Zhao, Da-Chuan; Allen, Annette D.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1993 , vol. 115, # 22 p. 10097 - 10103
反应条件
lithium diisopropyl amide
参考文献
Lejkowski, Michal; Banerjee, Prabal; Raabe, Gerhard; Runsink, Jan; Gais, Hans-Joachim
European Journal of Organic Chemistry, 2014 , vol. 2014, # 3 p. 529 - 553
参考文献
Birkofer,L. et al.
Chemische Berichte, 1962 , vol. 95, p. 971 - 976
反应条件
lithium diisopropyl amide in diethyl ether; hexane soln. of acetate is dropwise added to LDA (prepd. from n-Buli (hexane) and diisopropylamine) in ether at -78°C (N2), stirring for 1 h, chlorotrimethylgermane is added in ether, addnl. stirring at -78°C for 3.5 h; aq. NH4Cl is added, aq. layer extd. (benzene), washed (H2O, aq. NaCl), dried (MgSO4), concd., distn.; elem. anal.;
参考文献
Inoue, Sumie; Sato, Yoshiro; Suzuki, Tomoko
Organometallics, 1988 , vol. 7, p. 739 - 743
反应条件
tetrabutyl ammonium fluoride; fluorine 1.) CH2Cl2, -50 deg C, 2.) CH2Cl2, a) -50 deg C, 1 h, b) -50 to 0 deg C, 1 h, c) 0 deg C, 0.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kiselyov, Alexander S.; Strekowski, Lucjan
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4476 - 4478
反应条件
1: With C{N(2,6-iPr2C6H3)CH}2 in N,N-dimethyl-formamide T=0 - 20°C; Reformatsky Reaction; 24 h; Inert atmosphereGreen chemistry; 2: With hydrogenchloride in water; N,N-dimethyl-formamide Reformatsky Reaction; 0.5 h; Inert atmosphereGreen chemistry; SolventReagent/catalyst;
参考文献
Zou, Xiao-Lei; Du, Guang-Fen; Sun, Wan-Fu; He, Lin; Ma, Xiao-Wei; Gu, Cheng-Zhi; Dai, Bin
Tetrahedron, 2013 , vol. 69, # 2 p. 607 - 612
反应条件
cesium fluoride T=20°C; 3 h; closed vessel;
参考文献
Latouche, Regine; Texier-Boullet, Francoise; Hamelin, Jack
Tetrahedron Letters, 1991 , vol. 32, # 9 p. 1179 - 1182
反应条件
magnesium oxide; cesium fluoride 0.05 h; under microwave irradiation;
参考文献
Latouche, Regine; Texier-Boullet, Francoise; Hamelin, Jack
Tetrahedron Letters, 1991 , vol. 32, # 9 p. 1179 - 1182
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 22 h; Ambient temperature;
参考文献
Nakamura, Eiichi; Hashimoto, Koichi; Kuwajima, Isao
Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 3 p. 805 - 808
反应条件
LiN(Cy)2 1.) THF, -78 deg C, 15 min, 2.) THF, from -78 deg C to 25 deg C, 4.5 h; Yield given. Multistep reaction;
参考文献
Patel; Vyas; Pandey; Tavares; Fernandes
Synthetic Communications, 1991 , vol. 21, # 18-19 p. 1935 - 1940
