2-[(Z)-2-戊烯基]环戊烯-1-酮合成路线 （共 38 条）
反应条件
1: 92 percent 2: 62 percent / Jones reagent / acetone View Scheme
参考文献
Ho, Tse-Lok; Shyu, Kuo-Feng
Journal of the Chinese Chemical Society, 1998 , vol. 45, # 2 p. 319 - 321
参考文献
Liu, Zhu-Jin; Rong, Guo-Bin
Synthetic Communications, 1986 , vol. 16, # 8 p. 871 - 876
反应条件
1: NaOMe / methanol / 10 h / 0 °C 2: 90 percent / adipic acid / 6 h / 190 °C View Scheme
参考文献
Matsuda, Isamu; Murata, Shizuaki; Izumi, Yusuke
Journal of Organic Chemistry, 1980 , vol. 45, # 2 p. 237 - 240
反应条件
tri-ruthenium(0)dodecacarbonyl in toluene
T=100°C; Pauson-Khand reaction; P=760 Torr;
参考文献
Itami, Kenichiro; Mitsudo, Koichi; Yoshida, Jun-Ichi
Angewandte Chemie - International Edition, 2002 , vol. 41, # 18 p. 3481 - 3484
反应条件
sodium hydroxide in diethyl ether; water
72 h;
参考文献
Ballini, Roberto; Petrini, Marino; Marotta, Emanuela
Synthetic Communications, 1989 , vol. 19, # 3and4 p. 575 - 584
反应条件
hydrogen; Lindlar's catalyst in butan-1-ol
P=760 Torr; 2 h; Ambient temperature;
参考文献
Kataoka, Hideaki; Yamada, Toshiro; Goto, Kuniaki; Tsuji, Jiro
Tetrahedron, 1987 , vol. 43, # 18 p. 4107 - 4112
反应条件
tris(n-butyl)phosphine oxide in toluene
T=110°C; P=26600 Torr; 36 h;
参考文献
Billington, David C.; Helps, I. Malcolm; Pauson, Peter L.; Thomson, William; Willison, Debra
Journal of Organometallic Chemistry, 1988 , vol. 354, p. 233 - 242
参考文献
Ho, Tse-Lok; Shyu, Kuo-Feng
Journal of the Chinese Chemical Society, 1998 , vol. 45, # 2 p. 319 - 321
反应条件
2: 1) NaH / 1) allylalcohol, mineral oil, 90 deg C, 3 h; 2) 100 deg C, 3-4 h
3: 85 percent Chromat. / Pd(OAc)2, PPh3 / acetonitrile / 0.5 h / 80 °C / Heating; effect and amount of different catalyst and solvent
4: 95 percent / H2 / Lindlar catalyst / butan-1-ol / 2 h / 760 Torr / Ambient temperature
View Scheme
参考文献
Kataoka, Hideaki; Yamada, Toshiro; Goto, Kuniaki; Tsuji, Jiro
Tetrahedron, 1987 , vol. 43, # 18 p. 4107 - 4112
反应条件
1: 1) NaH / 1) allylalcohol, mineral oil, 90 deg C, 3 h; 2) 100 deg C, 3-4 h
2: 85 percent Chromat. / Pd(OAc)2, PPh3 / acetonitrile / 0.5 h / 80 °C / Heating; effect and amount of different catalyst and solvent
3: 95 percent / H2 / Lindlar catalyst / butan-1-ol / 2 h / 760 Torr / Ambient temperature
View Scheme
参考文献
Kataoka, Hideaki; Yamada, Toshiro; Goto, Kuniaki; Tsuji, Jiro
Tetrahedron, 1987 , vol. 43, # 18 p. 4107 - 4112
