benzene-d6 in benzene-d6
N2 or Ar atmosphere; addn. of C6D6 and HMn(CO)5 to mixt. of CH3Mn(CO)5 and bibenzyl (NMR tube, room temp., 21 h); not sepd.; (1)H-NMR spectroscopy;
参考文献
Bullock, R. Morris; Rappoli, Brian J.
Journal of the American Chemical Society, 1991 , vol. 113, # 5 p. 1659 - 1669
perchloric acid; Annogen in water
T=24.9°C; primary kinetic isotope effect in comparison with ethanol;
参考文献
Mukherjee, Jogeshwar; Banerji, Kalyan K.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, # 4 p. 394 - 395
→
反应条件
in benzene-d6
N2 or Ar atmosphere; addn. of C6D6 and DMn(CO)5 to mixt. of CH3Mn(CO)5 and 1,4-bis(trimethylsilyl)benzene (NMR tube, room temp., 24 h); not sepd.; (1)H-NMR spectroscopy;
参考文献
Bullock, R. Morris; Rappoli, Brian J.
Journal of the American Chemical Society, 1991 , vol. 113, # 5 p. 1659 - 1669