1: With pyridine; NBun4MnO4 T=60°C; 2 h; 2: With water T=20°C; 0.5 h; Product distribution / selectivity;

T=5 - 15°C;

(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate; 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane in dichloromethane; dimethyl sulfoxide T=85°C; 3 h; Schlenk techniqueInert atmosphere;

triethylamine; palladium on activated charcoal in carbon dioxide T=80°C; P=75006 Torr; 60 h;

triethylamine; acrylic acid methyl ester; palladium on activated charcoal in carbon dioxide T=80°C; P=75006 Torr; 60 h;

1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate / dimethyl sulfoxide; dichloromethane / 3 h / 85 °C / |Schlenk technique; |Inert atmosphere 2: 2,2'-azo-bisisobutyronitrile; N-bromosuccinmide / acetonitrile / 8 h / |Reflux View Scheme