9,10-anthracenedicarbonitrile; oxygen in acetonitrile-D3 T=40°C; 0.666667 h; Irradiationphotoinduced oxidation of benzyl phenyl sulfides promoted by 9,10-dicyanoanthracene; electron transfer reactions; reaction pathways for sulfide radical cation formed; C-S and C-H bond cleavage, S-oxidation; stability of photoproducts; Product distribution;
K5CoIIIW12O40; potassium acetate in water T=40°C; var. reag: PhIO, H2O2 or enzymatic oxidations: other products; biomimetic oxidation; Product distributionMechanism;
参考文献
Baciocchi, Enrico; Lanzalunga, Osvaldo; Marconi, Francesco
Tetrahedron Letters, 1994 , vol. 35, # 52 p. 9771 - 9774
9,10-anthracenedicarbonitrile; oxygen in acetonitrile-D3 T=40°C; 0.666667 h; Irradiationphotoinduced oxidation of benzyl phenyl sulfides promoted by 9,10-dicyanoanthracene; electron transfer reactions; reaction pathways for sulfide radical cation formed; C-S and C-H bond cleavage, S-oxidation; stability of photoproducts; Product distribution;