1-(3,4-环氧-4-甲基戊基)-1-甲基烯丙基乙酸酯合成路线 (共 4 条)
反应条件
pyridine; dihydrogen peroxide; methyltrioxorhenium (VII) in dichloromethane; water
T=-0.15°C; 1.5 h;
参考文献
Villa De P., Aida L.; De Vos, Dirk E.; Montes De C., Consuelo; Jacobs, Pierre A.
Tetrahedron Letters, 1998 , vol. 39, # 46 p. 8521 - 8524
反应条件
lt;Fe3O(piv)3(MeOH)3gt;Cl; oxygen
T=60°C; P=760 Torr; 20 h;
参考文献
Ito, Satoru; Inoue, Koh; Mastumoto, Masakatsu
Journal of the American Chemical Society, 1982 , vol. 104, # 23 p. 6450 - 6452
反应条件
dihydrogen peroxide; Amberlite IRA 900; PW4O24[(C4H9)4N]3 in acetonitrile
T=38°C; Epoxidation; 24 h;
参考文献
De Villa P., Aida L.; Sels, Bert F.; De Vos, Dirk E.; Jacobs, Pierre A.
Journal of Organic Chemistry, 1999 , vol. 64, # 19 p. 7267 - 7270
反应条件
potassium hydroxide; sulfuric acid
1.) 0 deg. C, H2O, 2 h; 2.) 100 deg C, 1 h; Multistep reaction;
参考文献
Williams, Patrick J.; Strauss, Christopher R.; Wilson, Bevan
Phytochemistry (Elsevier), 1980 , vol. 19, p. 1137 - 1140