3-戊基-2-环氧乙烷甲醛合成路线 (共 9 条)
反应条件
oxygen; polymer supported perruthenate in toluene
T=75°C; 6 h;
参考文献
Hinzen, Berthold; Lenz, Roman; Ley, Steven V.
Synthesis, 1998 , # 7 p. 977 - 979
反应条件
dihydrogen peroxide; sodium hydroxide in water
pH=8 - 8.5; 2 h;
参考文献
Gupta, Neeraj; Kaur, Manvinder; Shallu; Gupta, Neeru; Kad, Goverdhan Lal; Singh, Jasvinder
Natural Product Research, 2013 , vol. 27, # 6 p. 548 - 553
反应条件
1: With C76H56N2O2; Nb(OiPr)5 in chloroform; sodium chloride
T=40°C; 0.5 h;
2: With dihydrogen peroxide in chloroform; water; sodium chloride
T=40°C; enantioselective reaction;
参考文献
Egami, Hiromichi; Oguma, Takuya; Katsuki, Tsutomu
Journal of the American Chemical Society, 2010 , vol. 132, # 16 p. 5886 - 5895
反应条件
1: calcium carbonate; bromine / chloroform / 36 h / 10 - 15 °C
2: Ionicliquid [bmim]HSO4 / 0.08 h / |Microwave irradiation
3: sodium ethanolate / dimethyl sulfoxide / 16 h / 120 °C
4: water / 0.13 h / |Microwave irradiation
5: dihydrogen peroxide; sodium hydroxide / water / 2 h / pH 8 - 8.5
View Scheme
参考文献
Gupta, Neeraj; Kaur, Manvinder; Shallu; Gupta, Neeru; Kad, Goverdhan Lal; Singh, Jasvinder
Natural Product Research, 2013 , vol. 27, # 6 p. 548 - 553
反应条件
1: Ionicliquid [bmim]HSO4 / 0.08 h / |Microwave irradiation
2: sodium ethanolate / dimethyl sulfoxide / 16 h / 120 °C
3: water / 0.13 h / |Microwave irradiation
4: dihydrogen peroxide; sodium hydroxide / water / 2 h / pH 8 - 8.5
View Scheme
参考文献
Gupta, Neeraj; Kaur, Manvinder; Shallu; Gupta, Neeru; Kad, Goverdhan Lal; Singh, Jasvinder
Natural Product Research, 2013 , vol. 27, # 6 p. 548 - 553
反应条件
1: sodium ethanolate / dimethyl sulfoxide / 16 h / 120 °C
2: water / 0.13 h / |Microwave irradiation
3: dihydrogen peroxide; sodium hydroxide / water / 2 h / pH 8 - 8.5
View Scheme
参考文献
Gupta, Neeraj; Kaur, Manvinder; Shallu; Gupta, Neeru; Kad, Goverdhan Lal; Singh, Jasvinder
Natural Product Research, 2013 , vol. 27, # 6 p. 548 - 553
反应条件
1: water / 0.13 h / |Microwave irradiation
2: dihydrogen peroxide; sodium hydroxide / water / 2 h / pH 8 - 8.5
View Scheme
参考文献
Gupta, Neeraj; Kaur, Manvinder; Shallu; Gupta, Neeru; Kad, Goverdhan Lal; Singh, Jasvinder
Natural Product Research, 2013 , vol. 27, # 6 p. 548 - 553
反应条件
HOF* CH3CN in chloroform
T=0 - 20°C; Product distribution;
参考文献
Dayan; Ben-David; Rozen
Journal of Organic Chemistry, 2000 , vol. 65, # 25 p. 8816 - 8818
反应条件
in tetrahydrofuran
T=-78 - 20°C;
参考文献
Yu, Libing; Wang, Zhiqin
Journal of the Chemical Society, Chemical Communications, 1993 , # 3 p. 232 - 234