tetra(n-butyl)ammonium hydrogensulfate; silver carbonate; palladium diacetate in acetonitrile
1) rt, overnight, 2) 50 deg C, 5-8 h, various concentrations of nBu4NHSO4; other vinylic halides, other allylic alcohol, high regio- and stereoselectivity; Product distribution;
magnesium; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
1 h; Ambient temperature;
参考文献
Negishi, Ei-ichi; Takahashi, Tamotsu; Baba, Shigeru; Horn, David E. Van; Okukado, Nobuhisa
Journal of the American Chemical Society, 1987 , vol. 109, # 8 p. 2393 - 2401