2-[(二甲氨基)甲基]吡啶合成路线 （共 6 条）
反应条件
cis-[Ru(dimethyl sulfoxide)4Cl2]; phenyl silane; di-(1-adamantyl)-n-butylphosphine in toluene T=100°C; P=22502.3 Torr; AutoclaveInert atmosphere;
参考文献
Li, Yuehui; Fang, Xianjie; Junge, Kathrin; Beller, Matthias
Angewandte Chemie - International Edition, 2013 , vol. 52, # 36 p. 9568 - 9571
Angew. Chem., 2013 , vol. 125, # 36 p. 9747 - 9750,4
反应条件
1: With formic acid in water 18 h; Inert atmosphereReflux; 2: With sodium hydroxide in water Inert atmosphereCooling;
参考文献
Schley, Nathan D.; Dobereiner, Graham E.; Crabtree, Robert H.
Organometallics, 2011 , vol. 30, # 15 p. 4174 - 4179
反应条件
PPA T=180°C; 6 h; Yield given. Yields of byproduct given;
参考文献
Czuba, W.; Wodzinska, J.
Polish Journal of Chemistry, 1994 , vol. 68, # 7 p. 1343 - 1346
反应条件
sodium hydroxide; palladium on activated charcoal Hydrogenation;
参考文献
Morikawa
Yakugaku Zasshi, <1955> 593, 595 1956 , p. 5656
反应条件
(batho)2CuII (batho = 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolinedisulfonate); water in methanol T=25°C; 24 h; pH 8; Rate constant;
参考文献
Wang, Fengjiang; Sayre, Lawrence M.
Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 248 - 255
反应条件
(batho)2CuII (batho = 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolinedisulfonate); water in methanol T=25°C; 24 h; pH 8; Rate constant;
参考文献
Wang, Fengjiang; Sayre, Lawrence M.
Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 248 - 255
