2,2,2-三氟苯乙酮合成路线 （共 295 条）
反应条件
potassium hydride in dimethyl sulfoxide T=-10°C; trifluoromethylation; 3.5 h;
参考文献
Russell, Jamie; Roques, Nicolas
Tetrahedron, 1998 , vol. 54, # 45 p. 13771 - 13782
反应条件
1: With trifluorormethanesulfonic acid in dichloromethane T=0 - 20°C; Houben-Hoesch reaction; Inert atmosphere; 2: With water in dichloromethane Houben-Hoesch reaction; Cooling with ice;
参考文献
Raja, Erum K.; Klumpp, Douglas A.
Tetrahedron Letters, 2011 , vol. 52, # 40 p. 5170 - 5172
反应条件
1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranylidenamino]-2Λ54Λ5-catenadi(phosphazene) in tetrahydrofuran; hexane T=-40°C; 1 h; Inert atmosphere; TimeConcentration;
参考文献
Zhang, Yuan; Fujiu, Motohiro; Serizawa, Hiroki; Mikami, Koichi
Journal of Fluorine Chemistry, 2013 , vol. 156, p. 367 - 371
反应条件
1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranylidenamino]-2Λ54Λ5-catenadi(phosphazene) in tetrahydrofuran; hexane T=-40°C; 1.5 h; Inert atmosphere;
参考文献
Zhang, Yuan; Fujiu, Motohiro; Serizawa, Hiroki; Mikami, Koichi
Journal of Fluorine Chemistry, 2013 , vol. 156, p. 367 - 371
反应条件
water; boric acid in ethanol T=80°C; 8 h;
参考文献
Barton, Derek H. R.; Jaszberenyi, Joseph Cs.; Theodorakis, Emmanouil A.; Reibenspies
Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8050 - 8059
反应条件
1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in ethyl acetate 13 h; Reflux;
参考文献
Cheng, Huicheng; Pei, Yu; Leng, Faqiang; Li, Jingya; Liang, Apeng; Zou, Dapeng; Wu, Yangjie; Wu, Yusheng
Tetrahedron Letters, 2013 , vol. 54, # 33 p. 4483 - 4486
反应条件
water; boric acid in ethanol T=80°C; 8 h;
参考文献
Barton, Derek H. R.; Jaszberenyi, Joseph Cs.; Theodorakis, Emmanouil A.; Reibenspies
Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8050 - 8059
反应条件
water; boric acid in ethanol T=80°C; 8 h; Title compound not separated from byproducts;
参考文献
Barton, Derek H. R.; Jaszberenyi, Joseph Cs.; Theodorakis, Emmanouil A.; Reibenspies
Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8050 - 8059
反应条件
water; boric acid in ethanol T=80°C; 8 h;
参考文献
Barton, Derek H. R.; Jaszberenyi, Joseph Cs.; Theodorakis, Emmanouil A.; Reibenspies
Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8050 - 8059
反应条件
water; boric acid in ethanol T=80°C; 8 h; Title compound not separated from byproducts;
参考文献
Barton, Derek H. R.; Jaszberenyi, Joseph Cs.; Theodorakis, Emmanouil A.; Reibenspies
Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8050 - 8059
