2,5-二甲基-3,4-己烷二酮合成路线 （共 11 条）
反应条件
1: 65 percent / triethylamine / dimethylformamide / 48 h / Heating 2: 90 percent / SCl2 / various solvent(s); CCl4 / 0.25 h / 40 °C 3: various solvent(s); CCl4 / 1.5 h / Heating 4: 97 percent / CH2Cl2 / 4 h / Ambient temperature 5: 90 percent / NaOH / hexane; H2O 6: 100 percent / 2,2,4-trimethyl-pentane / 0.25 h / Heating 7: 28 percent / methanol / 3 h / Irradiation View Scheme
参考文献
Bolster, John M.; Kellogg, Richard M.
Journal of Organic Chemistry, 1982 , vol. 47, # 23 p. 4429 - 4439
反应条件
sodium ethanolate; benzene
参考文献
Snell; McElvain
Journal of the American Chemical Society, 1931 , vol. 53, p. 752,754
Org.Synth.Coll., 1943 , vol. Vol.II, p. 115
反应条件
beim folgenden Behandeln mit Schwefelsaeure;
参考文献
Snell; McElvain
Journal of the American Chemical Society, 1931 , vol. 53, p. 752,754
Org.Synth.Coll., 1943 , vol. Vol.II, p. 115
反应条件
hydrogenchloride; acetic acid; zinc
48 h; Ambient temperature;
参考文献
Floris, Barbara; Luchetti, Luciana; Rosnati, Vittorio
Tetrahedron, 1993 , vol. 49, # 20 p. 4409 - 4418
反应条件
1: 65 percent / triethylamine / dimethylformamide / 48 h / Heating
2: 90 percent / SCl2 / various solvent(s); CCl4 / 0.25 h / 40 °C
3: various solvent(s); CCl4 / 1.5 h / Heating
4: 97 percent / CH2Cl2 / 4 h / Ambient temperature
5: 90 percent / NaOH / hexane; H2O
6: 100 percent / 2,2,4-trimethyl-pentane / 0.25 h / Heating
7: 5 percent / Raney-Nickel (W5) / ethanol / 4 h / Heating
View Scheme
参考文献
Bolster, John M.; Kellogg, Richard M.
Journal of Organic Chemistry, 1982 , vol. 47, # 23 p. 4429 - 4439
反应条件
hydrogenchloride; acetic acid; zinc
48 h; Ambient temperature;
参考文献
Floris, Barbara; Luchetti, Luciana; Rosnati, Vittorio
Tetrahedron, 1993 , vol. 49, # 20 p. 4409 - 4418
反应条件
sodium amalgam; diethyl ether
参考文献
Krestinski; Bashenowa-Koslowskaja
Chemische Berichte, 1933 , vol. 66, p. 98
Zhurnal Obshchei Khimii, 1932 , vol. 2, p. 832
参考文献
Krestinski; Bashenowa-Koslowskaja
Zhurnal Obshchei Khimii, 1932 , vol. 2, p. 833
Chemische Berichte, 1933 , vol. 66, p. 98
反应条件
ethanol; sodium hydrogencarbonate; sodium hydrogensulfite
参考文献
Campbell et al.
Journal of the Chemical Society, 1950 , p. 2743
Full Text Show Details
Allen and Hanburys
Patent: US2665275 , 1950 ;
反应条件
sodium ethanolate; benzene
参考文献
Snell; McElvain
Journal of the American Chemical Society, 1931 , vol. 53, p. 752,754
Org.Synth.Coll., 1943 , vol. Vol.II, p. 115
