四(二乙基胺基)钛(IV)合成路线 （共 14 条）
反应条件
1: in hexanes T=-2 - 20°C; 2: With n-butyllithium in hexanes T=20°C; Cooling with acetone-dry ice;
参考文献
ALBEMARLE CORPORATION
Patent: WO2009/108930 A1, 2009 ;
Location in patent: Page/Page column 7-8 ;
反应条件
1: n-butyllithium; diethylamine in hexane T=-7 - 26°C; 0.25 - 3.33333 h; 2: titanium bis(diethylamido)dichloride; ClTi(NEt2)3 in tetrahydrofuran; hexane T=20 - 38°C; 0.833333 - 48 h;
参考文献
Albemarle Corporation
Patent: US6831188 B1, 2004 ;
Location in patent: Page/Page column 8-12 ;
反应条件
C4H9Li in hexane; toluene (N2); glovebox; soln. of BuLi in hexane was added to soln. of NHEt2 in toluene; stirred overnight; toluene was added; Ti compd. was added; refluxed overnight; distd. (vac., 300°C);
参考文献
Gueta-Neyroud, Tal; Tumanskii, Boris; Botoshansky, Mark; Eisen, Moris S.
Journal of Organometallic Chemistry, 2007 , vol. 692, # 5 p. 927 - 939
反应条件
in toluene under N2; TiCl4(thf)2 added in small portions to soln. of LiNEt2 in toluene, stirred overnight at room temp., heated at 100°C for severalhours; toluene replaced with pentane, soln. filtered, extd. before the solvent was removed, dried under vac.;
参考文献
Morgan, Alicia R.; Kloskowski, Michael; Kalischewski, Felix; Phillips, Aaron H.; Petersen, Jeffrey L.
Organometallics, 2005 , vol. 24, # 22 p. 5383 - 5392
反应条件
in not given under Ar or N2, prepn. in accordance with the method of Bradley and Thomas (J. Chem. Soc. (London) (1960), 3857), except TiCl4(THF)2 employed instead of TiCl4 and react. carried out at room temp.;
参考文献
Naiini, A. A.; Ringrose, S. L.; Su, Y.; Jacobson, R. A.; Verkade, J. G.
Inorganic Chemistry, 1993 , vol. 32, p. 1290 - 1296
反应条件
in dichloromethane T=25°C; 36 h;
参考文献
Hosomi, Akira; Yanagi, Toshiharu; Hojo, Makoto
Tetrahedron Letters, 1991 , vol. 32, # 21 p. 2371 - 2374
反应条件
in benzene Ambient temperature; Product distributionMechanism;
参考文献
Vather, S. M.; Modro, T. A.
Phosphorus and Sulfur and the Related Elements, 1986 , vol. 26, p. 383 - 385
反应条件
in benzene T=45°C; 24 h; Product distributionMechanism;
参考文献
Vather, S. M.; Modro, T. A.
Phosphorus and Sulfur and the Related Elements, 1986 , vol. 26, p. 383 - 385
反应条件
in benzene T=45°C; 48 h; Product distributionMechanism;
参考文献
Vather, S. M.; Modro, T. A.
Phosphorus and Sulfur and the Related Elements, 1986 , vol. 26, p. 383 - 385
反应条件
in diethyl ether room temp.;
参考文献
Steinborn, Dirk; Thies, Bettina; Wagner, Ines; Taube, Rudolf
Zeitschrift fuer Chemie (Stuttgart, Germany), 1989 , vol. 29, # 9 p. 333 - 334
