1,1,3-三甲基环戊烷合成路线 （共 79 条）
反应条件
lithium diisopropyl amide in diethyl ether T=0°C; Further byproducts given;
参考文献
Ashby, E. C.; Park, B.; Patil, G. S.; Gadru, K.; Gurumurthy, R.
Journal of Organic Chemistry, 1993 , vol. 58, p. 424 - 437
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=25°C; 21 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Ashby, E. C.; Deshpande, Abhay K.
Journal of Organic Chemistry, 1994 , vol. 59, # 14 p. 3798 - 3805
反应条件
magnesium in tetrahydrofuran T=25°C; 8 h; Further byproducts given;
参考文献
Ashby, E. C.; Deshpande, Abhay K.; Doctorovich, Fabio
Journal of Organic Chemistry, 1994 , vol. 59, # 21 p. 6223 - 6232
反应条件
magnesium in tetrahydrofuran T=25°C; 8 h; Further byproducts given;
参考文献
Ashby, E. C.; Deshpande, Abhay K.; Doctorovich, Fabio
Journal of Organic Chemistry, 1994 , vol. 59, # 21 p. 6223 - 6232
反应条件
1: diethyl ether 2: HCl / 2 °C 3: xylene / 40 °C View Scheme
参考文献
McKinley; Stevens; Baldwin
Journal of the American Chemical Society, 1945 , vol. 67, p. 1455,1458
反应条件
anhydrous butyl ether
参考文献
McKinley; Stevens; Baldwin
Journal of the American Chemical Society, 1945 , vol. 67, p. 1455,1458
Full Text Show Details
Gulf Research and Devel. Co.
Patent: US2415599 , 1944 ;
反应条件
T=370 - 460°C; P=29420.3 - 275815 Torr;
参考文献
McKinley; Stevens; Baldwin
Journal of the American Chemical Society, 1945 , vol. 67, p. 1455,1458
Full Text Show Details
Gulf Research and Devel. Co.
Patent: US2415454 , 1944 ;
Full Text Show Details
Gulf Research and Devel. Co.
Patent: US2415438 , 1944 ;
反应条件
dicyclo-hexylphosphine in N,N,N',N',N'',N''-hexamethylphosphoric triamide T=24°C; 4 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Ashby, E.C.; Argyropoulos, J.N.
Tetrahedron Letters, 1984 , vol. 25, # 1 p. 7 - 10
反应条件
lithium anion of 1,3-dithiane in hexane 1) -20 deg C, 90 min, 2) RT, 2h;
参考文献
Juaristi, Eusebio; Jimenez-Vazquez, Hugo A.
Journal of Organic Chemistry, 1991 , vol. 56, # 4 p. 1623 - 1630
反应条件
1: HCl / 20 h / 0 °C 2: 1) Mg / THF 3: LiAlH4 / diethyl ether / 0 °C 4: 6.6 g / Br2 / PPh3 / pyridine / 20 h / Heating 5: 7.5 percent Chromat. / LiAlH4 / tetrahydrofuran / 480 h / Ambient temperature View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
