1,1,3-三甲基环戊烷合成路线 （共 79 条）
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide in tetrahydrofuran 10 h; Ambient temperatureother alkyl halides and tosylate, var. solvents, other reaction times, in the presence or absence of light and radical scavenger, also in the presence of 1,4-cyclohexadiene and dicyclohexylphosphine; Product distributionMechanism;
参考文献
Ashby, E. C.; Argyropoulos, J. N.
Journal of Organic Chemistry, 1985 , vol. 50, # 18 p. 3274 - 3283
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=25°C; 21 h; also with LAD in THF-d8; other time; various ratio of the title compound to LAH; Product distributionMechanism;
参考文献
Ashby, E. C.; Deshpande, Abhay K.
Journal of Organic Chemistry, 1994 , vol. 59, # 14 p. 3798 - 3805
反应条件
magnesium in tetrahydrofuran T=25°C; 8 h; also in THF-d8; Quenching with D2O; in the presence of a radicaltrap - DCPH; Mechanism;
参考文献
Ashby, E. C.; Deshpande, Abhay K.; Doctorovich, Fabio
Journal of Organic Chemistry, 1994 , vol. 59, # 21 p. 6223 - 6232
反应条件
magnesium in tetrahydrofuran T=25°C; 8 h; also in THF-d8; Quenching with D2O; in the presence of a radicaltrap - DCPH; Mechanism;
参考文献
Ashby, E. C.; Deshpande, Abhay K.; Doctorovich, Fabio
Journal of Organic Chemistry, 1994 , vol. 59, # 21 p. 6223 - 6232
反应条件
naphthalenyllithium in tetrahydrofuran T=25°C; also in THF-d8; deuterium-labelling experiments; Product distributionMechanism;
参考文献
Ashby, E. C.; Desphande, Abhay K.
Journal of Organic Chemistry, 1995 , vol. 60, # 14 p. 4530 - 4535
参考文献
Mark; Pines
Journal of the American Chemical Society, 1956 , vol. 78, p. 5946,5947
反应条件
hydrogen; tantalum T=213.9°C; KineticsProduct distributionThermodynamic data;
参考文献
Clarke, John K. A.; Hegarty, Bernard F.; Rooney, John J.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1988 , vol. 84, # 7 p. 2511 - 2518
反应条件
hydrogen; palladium T=201.9°C; on sintered platinum-metal films; KineticsProduct distribution;
参考文献
Clarke, John K. A.; Hegarty, Bernard F.; Rooney, John J.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1988 , vol. 84, # 7 p. 2511 - 2518
反应条件
hydrogen; zirconium T=423.9°C; KineticsProduct distributionThermodynamic data;
参考文献
Clarke, John K. A.; Hegarty, Bernard F.; Rooney, John J.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1988 , vol. 84, # 7 p. 2511 - 2518
反应条件
dicyclo-hexylphosphine in tetrahydrofuran 96 h; other solvents, other radical trap, other lithium thiolates; Product distributionMechanism;
参考文献
Ashby, E. C.; Park, W. S.; Goel, A. B.; Su, Wei-Yang
Journal of Organic Chemistry, 1985 , vol. 50, # 25 p. 5184 - 5193
