1,4-双(三甲硅基)-1,3-丁二炔合成路线 （共 93 条）
反应条件
N,N,N',N,-tetramethylethylenediamine; oxygen; copper(l) chloride in acetone Hay homocoupling;
参考文献
Klinger, Christian; Vostrowsky, Otto; Hirsch, Andreas
European Journal of Organic Chemistry, 2006 , # 6 p. 1508 - 1524
反应条件
N,N,N',N,-tetramethylethylenediamine; oxygen; copper(l) chloride in acetone Hay homocoupling; 24 h;
参考文献
Klinger, Christian; Vostrowsky, Otto; Hirsch, Andreas
European Journal of Organic Chemistry, 2006 , # 6 p. 1508 - 1524
反应条件
bis(benzonitrile)palladium(II) dichloride; copper diacetate; diisopropylamine; triphenylphosphine 3 h; Heating;
参考文献
Journal of Organic Chemistry, , vol. 53, # 11 p. 2489 - 2496
反应条件
N,N,N',N,-tetramethylethylenediamine; oxygen; copper(l) chloride in acetone T=20°C; 24 h;
参考文献
Zhao, Yuming; McDonald, Robert; Tykwinski, Rik R.
Journal of Organic Chemistry, 2002 , vol. 67, # 9 p. 2805 - 2812
反应条件
N-butylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in benzene 1 h; Ambient temperature;
参考文献
Tetrahedron Letters, , vol. 26, # 6 p. 709 - 712
反应条件
N,N,N',N,-tetramethylethylenediamine; oxygen; copper(l) chloride in acetone Hay homocoupling;
参考文献
Klinger, Christian; Vostrowsky, Otto; Hirsch, Andreas
European Journal of Organic Chemistry, 2006 , # 6 p. 1508 - 1524
反应条件
T=-50 - -40°C; 15 h;
参考文献
Stracker, Elaine C.; Zweifel, George
Tetrahedron Letters, 1990 , vol. 31, # 47 p. 6815 - 6818
反应条件
in dichloromethane 12 h; Ambient temperature;
参考文献
Synthesis, , # 1 p. 100 - 106
反应条件
in tetrahydrofuran under N2; Ti complex reacted with Cu(OC(O)CH3)2 (molar ratio 1:1) in THF at 25°C for 30 min; solvent removed in vac.; chromd. (Kieselgur, -30°C, n-pentane); eluted with n-pentane (Me3SiC4SiMe3) and THF (Ti-Cu complex);
参考文献
Journal of Organometallic Chemistry, , vol. 601, # 2 p. 226 - 232
反应条件
in tetrahydrofuran byproducts: Pd; under N2; PdCl2 in THF reacted with equimolar amt. of Ti complex in THFfor 3 h at 25°C; filtered through Kieselgur; volatiles removed in vac.; sepd. by chromy.(Kieselgel, -20°C, n-pentane); eluted with n-pentane (Me3SiC4SiMe3) and CH2Cl2 (Ti complex);
参考文献
Journal of Organometallic Chemistry, , vol. 601, # 2 p. 226 - 232
