4-甲氧苯重氮四氟硼酸盐合成路线 （共 231 条）
反应条件
potassium hydroxide 1.) DMSO, 50 min; 2.) DMSO/H2O, 50 min, r.t.; Yield given. Multistep reaction;
参考文献
Petrillo, Giovanni; Novi, Marino; Garbarino, Giacomo; Filiberti, Marcos
Tetrahedron, 1989 , vol. 45, # 23 p. 7411 - 7420
反应条件
1: 1-bromo-1-phenyl-ethane With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; zinc in tetrahydrofuran T=50°C; 6 h; Inert atmosphere; 2: 4-methoxybenzenediazonium tetrafluoroborate With zinc dibromide in tetrahydrofuran T=-60 - 25°C; Inert atmosphere; 3: With chloro-trimethyl-silane in tetrahydrofuran T=125°C; 1.5 h; Inert atmosphereMicrowave irradiation; regioselective reaction;
参考文献
Haag, Benjamin A.; Zhang, Zhi-Guang; Li, Jin-Shan; Knochel, Paul
Angewandte Chemie - International Edition, 2010 , vol. 49, # 49 p. 9513 - 9516
反应条件
magnesium 1.) THF, reflux, 2.) THF, 30 deg C, 60 s; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Singh, P. R.; Khanna, R. K.; Jayaraman, B.
Tetrahedron Letters, 1982 , vol. 23, # 51 p. 5475 - 5478
反应条件
magnesium 1.) THF, reflux, 2.) THF, 30 deg C, 180 s; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Singh, P. R.; Khanna, R. K.; Jayaraman, B.
Tetrahedron Letters, 1982 , vol. 23, # 51 p. 5475 - 5478
反应条件
[(1,3-dimesitylimidazol-2-ylidene)(benzoquinone)Pd(0)]2 in methanol T=50°C; Heck reaction; 1 h;
参考文献
Selvakumar, Kumaravel; Zapf, Alexander; Spannenberg, Anke; Beller, Matthias
Chemistry - A European Journal, 2002 , vol. 8, # 17 p. 3901 - 3906
反应条件
magnesium 1.) THF, reflux, 2.) THF, 30 deg C, 60 s; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Singh, P. R.; Khanna, R. K.; Jayaraman, B.
Tetrahedron Letters, 1982 , vol. 23, # 51 p. 5475 - 5478
反应条件
palladium diacetate in methanol Heck arylation; 0.25 h; Heating;
参考文献
Pastre, Julio Cezar; Correia, Carlos Roque Duarte
Organic Letters, 2006 , vol. 8, # 8 p. 1657 - 1660
反应条件
[Cu(CH3CN)4]BF4; potassium nitrate in phosphate buffer T=24.84°C; Sandmeyer reaction; pH=7.00; KineticsProduct distribution; Further Variations:pH-valuesReagents;
参考文献
Organic and Biomolecular Chemistry, , vol. 5, # 4 p. 679 - 698
反应条件
in tetrahydrofuran T=-30°C; 1 h; also in DMSO and in the presence of 18-crown-6; Product distribution;
参考文献
Todres, Z. V.; Ovsepyan, G. Ts.; Ionina, E. A.; Kosnikov, A. Yu.; Lindeman, S. V.; Struchkov, Yu. T.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, p. 1651 - 1656
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 8 p. 1845 - 1852
反应条件
SIDip*HCl; palladium diacetate in tetrahydrofuran T=0°C; Sizuki-Miyaura cross coupling; 2.5 h;
参考文献
Karch, Ralf; Briel, Oliver; Kayser, Bernd; Beller, Matthias; Selvakumar, Kumaravel; Frisch, Anja; Zapf, Alexander
Patent: US2006/122398 A1, 2006 ;
Location in patent: Page/Page column 8-9 ;
