6-甲基-5-庚烯-2-醇合成路线 （共 96 条）
反应条件
hydrogen; palladium on activated charcoal in ethanol 7 h;
参考文献
Alward, Sandra J.; Fallis, Alex G.
Canadian Journal of Chemistry, 1984 , vol. 62, p. 121 - 127
反应条件
sodium hydroxide; tris(triphenylphosphine)ruthenium(II) chloride in water T=185°C; P=7600 Torr; microwave irradiation;
参考文献
Chemistry Letters, , vol. 34, # 5 p. 664 - 665
反应条件
reusable unsupported rhenium nanocrystalline particle in neat (no solvent) T=180°C; 10 h; Green chemistry;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 3 p. 833 - 836
Angew. Chem., , vol. 126, # 03 p. 852 - 855,4
反应条件
4-(N,N-dimethlyamino)pyridine in dichloromethane T=20°C;
参考文献
Gupta, Pankaj; Sethi, Vijay K.; Taneja, Subhash C.; Shah, Bhahwal A.; Andotra, Samar S.; Koul, Surrinder; Chimni, Swapandeep S.; Qazi, Ghulam N.
Helvetica Chimica Acta, 2007 , vol. 90, # 1 p. 196 - 204
反应条件
di-isopropyl azodicarboxylate; triphenylphosphine in tetrahydrofuran T=180°C; Mitsunobu inversion; 0.116667 h; microwave irradiation;
参考文献
Steinreiber, Andreas; Stadler, Alexander; Mayer, Sandra F; Faber, Kurt; Kappe
Tetrahedron Letters, 2001 , vol. 42, # 36 p. 6283 - 6286
反应条件
Yield given. Yields of byproduct given;
参考文献
Wang, Yi-Fong; Yakovlevsky, Kirill; Zhang, Bailing; Margolin, Alexey L.
Journal of Organic Chemistry, 1997 , vol. 62, # 11 p. 3488 - 3495
反应条件
1: 42 percent / PBr3, pyridine / diethyl ether 2: 60 percent / dimethylsulfoxide 3: 67 percent / KOH / ethane-1,2-diol; H2O; ethanol / 18 h / Heating 4: 86 percent / oxalyl chloride, pyridine / benzene / 2 h / Ambient temperature 5: 76 percent / triethyl amine / diethyl ether / 1 h / Ambient temperature 6: 82 percent / diethyl ether / Ambient temperature 7: 38 percent / acetonitrile / Irradiation View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
Tris-HCl buffer T=30°C; pH=7.5; 24 h; Enzymatic reaction; enantioselective reaction;
参考文献
Bisogno, Fabricio R.; Lavandera, Ivan; Kroutil, Wolfgang; Gotor, Vicente
Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1730 - 1732
反应条件
trimethylsilyl chromates in dichloromethane T=25°C; 2 h;
参考文献
Moiseenkov, A. M.; Cheskis, B. A.; Veselovskii, A. B.; Veselovskii, V. V.; Romanovich, A. Ya.; Chizhov, O. S.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 9 p. 1646 - 1648
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 9 p. 1852 - 1854
反应条件
alcohol dehydrogenase from Lactobacillus kefir; YcnD-oxidoreductase; NADPH T=30°C; pH=7.5; 6 h; aq. bufferEnzymatic reaction; optical yield given as percent eeenantiospecific reaction;
参考文献
Voss, Constance V.; Gruber, Christian C.; Faber, Kurt; Knaus, Tanja; Macheroux, Peter; Kroutil, Wolfgang
Journal of the American Chemical Society, 2008 , vol. 130, # 42 p. 13969 - 13972
