6-甲基-5-庚烯-2-醇合成路线 （共 96 条）
反应条件
1: 42 percent / PBr3, pyridine / diethyl ether
2: 60 percent / dimethylsulfoxide
3: 67 percent / KOH / ethane-1,2-diol; H2O; ethanol / 18 h / Heating
View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
1: PPh3, CCl4 / 24 h / Heating
2: (i) Li, Na, hexane, (ii) /BRN= 2042049/
View Scheme
参考文献
Fetizon,M. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1979 , p. 1407 - 1410
反应条件
sulfuric acid
und Machen die erhaltene Loesung unter Kuehlung mit NaOH alkalisch;
参考文献
Rupe; Schlochoff
Chemische Berichte, 1905 , vol. 38, p. 1504
反应条件
pyridine; thionyl chloride
unter Eiskuehlung und nachfolgendem Erhitzen auf 160grad;
参考文献
Epstein, William W.; Grua, James R.; Gregonis, Donald
Journal of Organic Chemistry, 1982 , vol. 47, # 6 p. 1128 - 1131
参考文献
Helferich; Dommer
Chemische Berichte, 1920 , vol. 53, p. 2014
参考文献
Doeuvre
Bulletin de la Societe Chimique de France, 1929 , vol. <4>45, p. 359
反应条件
dicyclohexyl-carbodiimide; copper(l) chloride
参考文献
Badet,B.; Julia,M.; Mallet,J.M.
Tetrahedron, 1988 , vol. 44, p. 2913
反应条件
1: 74 percent / H2 / 10 percent Pd/C / ethanol / 7 h
2: 45 percent / 1.) triphenylphosphine, Br2, pyridine / acetonitrile / 0 °C
3: 45 percent / Na-Li alloy (2percent Na) / diethyl ether / 3.5 h / Irradiation
View Scheme
参考文献
Alward, Sandra J.; Fallis, Alex G.
Canadian Journal of Chemistry, 1984 , vol. 62, p. 121 - 127
反应条件
pyridine; phosphorus tribromide in diethyl ether
T=0 - 20°C; 3 h;
参考文献
Singh, Vasundhara; Khurana, Anupam; Kaur, Irvinder; Sapehiyia, Varinder; Kad, Goverdhan L.; Singh, Jasvinder
Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 15 p. 1766 - 1768
参考文献
Doeuvre
Bulletin de la Societe Chimique de France, 1929 , vol. <4>45, p. 359
Full Text Show Details
Bayer and Co.
Patent: ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 101
