in tetrahydrofuran
a suspn. of Rh complex in THF and MeCHCHCH2Br in 1:2 molar ratio sealedin vacuo in a Pyrex reaction tube was either stirred or shaken for 1 h at 20°C; volatiles were removed under vac., trapped at -196°C and analyzed by GLC, residue was chromd. using hexane followed by benzene or CHCl3 as eluent, and recrystd. from a mixt. of either CHCl3 and EtOH or benzene and MeOH;
参考文献
Booth, Brian L.; Casey, Geoffrey C.; Haszeldine, Robert N.
Journal of Organometallic Chemistry, 1982 , vol. 224, # 2 p. 197 - 205
Petrow
Zhurnal Obshchei Khimii, 1941 , vol. 11, p. 713,715, 719
Chem.Abstr., 1942 , p. 404
Full Text Show Details
Publicker Industries Inc.
Patent: US2423599 , 1944 ;
bis(cyclopentadienyl)titanium dichloride; manganese in tetrahydrofuran
T=20°C;
参考文献
Barrero, Alejandro F.; Herrador, M. Mar; Quilez Del Moral, Jose F.; Arteaga, Pilar; Arteaga, Jesus F.; Dieguez, Horacio R.; Sanchez, Elena M.
Journal of Organic Chemistry, 2007 , vol. 72, # 8 p. 2988 - 2995
