5,5'-二溴-2,2'-联噻吩合成路线 （共 35 条）
反应条件
1: 2-bromo-5-(5-bromothiophen-2-yl)thiophene With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: methyl trifluoromethanesulfonate in tetrahydrofuran; hexane T=0°C;
参考文献
Nagaki, Aiichiro; Takabayashi, Naofumi; Tomida, Yutaka; Yoshida, Jun-ichi
Organic Letters, 2008 , vol. 10, # 18 p. 3937 - 3940
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: With methanol in tetrahydrofuran; hexane T=0°C;
参考文献
Nagaki, Aiichiro; Takabayashi, Naofumi; Tomida, Yutaka; Yoshida, Jun-ichi
Organic Letters, 2008 , vol. 10, # 18 p. 3937 - 3940
反应条件
potassium phosphate; 2-(dimethylamino)-ethanol; copper(l) iodide; copper T=80°C; 48 h;
参考文献
Lu, Zhikuan; Twieg, Robert J.
Tetrahedron, 2005 , vol. 61, # 4 p. 903 - 918
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether 2 h; Heating;
参考文献
Pham, Chiem Van; Burkhardt, A.; Shabana, R.; Cunningham, David D.; Mark, Harry B.; Zimmer, Hans
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 46, p. 153 - 168
反应条件
Cl2Ni(1,2-bis(diphenylphosphino)ethane) Multistep reaction;
参考文献
Zamboni, R.; Ruani, G.; Taliani, C.; Pal, A. J.
Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 1992 , vol. 218, p. 113 - 116
反应条件
1: 2-bromo-3-(n-hexyl)thiophene With magnesium in diethyl ether 3 h; Heating; 2: 2-bromo-5-(5-bromothiophen-2-yl)thiophene With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether; benzene Heating;
参考文献
Kanato, Hiroki; Takimiya, Kazuo; Otsubo, Tetsuo; Aso, Yoshio; Nakamura, Takumi; Araki, Yasuyuki; Ito, Osamu
Journal of Organic Chemistry, 2004 , vol. 69, # 21 p. 7183 - 7189
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether; benzene Substitution; 5 h; Heating;
参考文献
Yamashiro, Takashi; Aso, Yoshio; Otsubo, Tetsuo; Tang, Heqing; Harima, Yutaka; Yamashita, Kazuo
Chemistry Letters, 1999 , # 5 p. 443 - 444
参考文献
Lee, Sang Kyu; Jung, Young Kwan; Shin, Won Suk; Shim, Hong-Ku; Moon, Sang-Jin
Molecular Crystals and Liquid Crystals, 2010 , vol. 520, p. 10 - 18
反应条件
1: 2-bromo-5-(5-bromothiophen-2-yl)thiophene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: N,N-dimethyl-formamide T=20°C; 2 h; Inert atmosphere;
参考文献
Kuo, Cheng-Yu; Huang, Yu-Chen; Hsiow, Chuen-Yo; Yang, Yu-Wen; Huang, Ching-I; Rwei, Syang-Peng; Wang, Hsing-Lin; Wang, Leeyih
Macromolecules, 2013 , vol. 46, # 15 p. 5985 - 5997
反应条件
N-bromosuccinmide in chloroform; acetic acid 72 h; Heating;
参考文献
Dahlmann, Uwe; Neidlein, Richard
Helvetica Chimica Acta, 1996 , vol. 79, # 3 p. 755 - 766
