十二碳-11-烯-2-酮合成路线 （共 33 条）
反应条件
copper(l) iodide in diethyl ether
参考文献
Back, Thomas G.; Kerr, Russell G.
Tetrahedron, 1985 , vol. 41, # 21 p. 4759 - 4764
反应条件
tetrabutyl ammonium fluoride in dimethyl sulfoxide
T=20°C; 4 h; Title compound not separated from byproducts.;
参考文献
Berube, Marie; Kamal, Fatima; Roy, Jenny; Poirier, Donald
Synthesis, 2006 , # 18 p. 3085 - 3091
反应条件
CrCl3(THF)3; chloro-trimethyl-silane; zinc in 1,4-dioxane
T=25°C; Addition; Elimination; Title compound not separated from byproducts;
参考文献
Takai, Kazuhiko; Ichiguchi, Tetsuya; Hikasa, Shintaro
Synlett, 1999 , # 8 p. 1268 - 1270
反应条件
1: undecylenic acid powder With sodium hydride in tetrahydrofuran
T=20°C; 0.5 h;
2: methyl iodide With strontium in tetrahydrofuran
T=20°C; 0.75 h;
参考文献
Miyoshi, Norikazu; Matsuo, Tsuyoshi; Asaoka, Masashi; Matsui, Aki; Wada, Makoto
Chemistry Letters, 2007 , vol. 36, # 1 p. 28 - 29
反应条件
trimethylaluminum; zinc
T=25°C; 4 h;
参考文献
Okazoe, Takashi; Hibino, Jun-ichi; Takai, Kazuhiko; Nozaki, Hitosi
Tetrahedron Letters, 1985 , vol. 26, # 45 p. 5581 - 5584
反应条件
hydrogen bromide in diethyl ether
Yield given;
参考文献
Back, Thomas G.; Kerr, Russell G.
Tetrahedron, 1985 , vol. 41, # 21 p. 4759 - 4764
反应条件
1: 598 mg / NaI / acetone / 24 h / Heating
2: tetrabutylammonium fluoride hydrate / dimethylsulfoxide / 4 h / 20 °C
View Scheme
参考文献
Berube, Marie; Kamal, Fatima; Roy, Jenny; Poirier, Donald
Synthesis, 2006 , # 18 p. 3085 - 3091
反应条件
1: 963 mg / tetrahydrofuran / 1 h / -78 - 0 °C
2: 598 mg / NaI / acetone / 24 h / Heating
3: tetrabutylammonium fluoride hydrate / dimethylsulfoxide / 4 h / 20 °C
View Scheme
参考文献
Berube, Marie; Kamal, Fatima; Roy, Jenny; Poirier, Donald
Synthesis, 2006 , # 18 p. 3085 - 3091
反应条件
in cyclohexane
T=15°C; Irradiation;
参考文献
Schulte-Elte,K.H. et al.
Helvetica Chimica Acta, 1971 , vol. 54, p. 1759 - 1767
反应条件
manganese(IV) oxide; aluminum oxide
Heating;
参考文献
Glinski; Gibka
Polish Journal of Chemistry, 2004 , vol. 78, # 2 p. 299 - 302
