in diethyl ether under N2 atm. Et2O soln. Grignard reagent was added dropwise for 2 h to stirred suspn. CdCl2 in Et2O in protected from light vessel and stirred for 12 h; Et2O was removed at reduced pressure;
参考文献
Tang, Hui; Richey Jr., Herman G.
Organometallics, 2001 , vol. 20, # 8 p. 1569 - 1574
Gilman; Nelson
Recueil des Travaux Chimiques des Pays-Bas, 1936 , vol. 55, p. 518,528, 529
Journal of the American Chemical Society, 1939 , vol. 61, p. 741
Gilman; Nelson
Recueil des Travaux Chimiques des Pays-Bas, 1936 , vol. 55, p. 518,528, 529
Journal of the American Chemical Society, 1939 , vol. 61, p. 741
Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J.; Owen, Jonathan S.
Journal of the American Chemical Society, 2013 , vol. 135, # 49 p. 18536 - 18548
in dichloromethane byproducts: CH3I; To a soln. of Cd-compd. the perflouriodoalkane is pipetted at -196°C, mixt. is allowed to warm to room temp., then mixt. is stirred for 2 d (under inert gas, without moisture).; Evapn. in high-vac. at 0-40°C, washing once with cold CH2Cl2.;
参考文献
Naumann, Dieter; Glinka, Klaus; Tyrra, Wieland
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1991 , vol. 594, p. 95 - 105
