in neat (no solvent) (N2); mixing of NaN(CN)2 and CI4 in agate mortar in 1:4 ratio; grinding for 5 min; placing in Cu container; pressing at 300 kg/cm**2 for 5 min; shock treatment (21 GPa); monitoring by XRD;
参考文献
Shibata, Kazusato; Sekine, Toshimori
Solid State Communications, 2006 , vol. 139, # 10 p. 501 - 505
sodium in ammonia byproducts: CH2I2, CHI3; tetraiodomethane addn. (in portions) to B-compd. and Na soln. (stirring), mixt. decompn. (water), extn. (ether); solvent driving off; GLC, mass and (11)B-NMR spectroscopy; total yield 15percent;
参考文献
Stanko, V. I.; Gol'tyapin, Yu. V.
Journal of General Chemistry USSR (English Translation), 1982 , vol. 52, p. 72 - 73
Zhurnal Obshchei Khimii, 1982 , vol. 52, p. 78 - 80
in neat (no solvent) vigorous reaction on shaking CI4 with IF5 at 90-100°C, reaction is finished after 30 min.;;
参考文献
Banks, A. A.; Emeleus, H. J.; Haszeldine, R. N.; Kerrigan, V.
Journal of the Chemical Society, 1948 , p. 2188 - 2190
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Gmelin Handbook: C: MVol.D2, 4.1.4.6, page 281 - 283
Emeleus, H. J.; Rao, G. S.
Journal of the Chemical Society, 1958 , p. 4245 - 4250
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Gmelin Handbook: C: MVol.D2, 4.2.4.1, page 314 - 314
