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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
5070-59-7
合成路线
(共 22 条)
19480-04-7
→
反应条件
5070-59-7
反应条件
Zr(OiPr)4·HOiPr; 4 Angstroem MS; 1,1'-binaphthyl-2,2'-diol in isopropyl alcohol; toluene T=20°C; 10 h;
参考文献
Lorca, Miguel; Kuhn, Dan; Kurosu, Michio
Tetrahedron Letters, 2001 , vol. 42, # 36 p. 6243 - 6246
109-49-9
5-已烯-2-酮
+
201230-82-2
→
反应条件
5070-59-7
反应条件
[rhodium(I)(carbonyl)2(acetylacetonate)]; trifluorormethanesulfonic acid; N-(5-diphenylphosphanylpyrrole-2-carbonyl)guanidine; hydrogen in dichloromethane T=40°C; P=30003 Torr; 24 h; Autoclave; regioselective reaction;
参考文献
Diab, Lisa; Smejkal, Tomas; Geier, Jens; Breit, Bernhard
Angewandte Chemie - International Edition, 2009 , vol. 48, # 43 p. 8022 - 8026
591-49-1
1-甲基-1-环己烯
→
反应条件
5070-59-7
反应条件
1: With oxygen; ozone; acetic acid in dichloromethane T=-4 - -2°C; 2: With sodium tris(acetoxy)borohydride in dichloromethane T=20°C; 3 h;
参考文献
Ishmuratov; Kharisov; Yakovleva; Botsman; Muslukhov; Tolstikov
Russian Journal of Organic Chemistry, 2001 , vol. 37, # 1 p. 37 - 39
627-27-0
3-丁烯-1-醇
+
67-64-1
丙酮
→
反应条件
5070-59-7
反应条件
tert-butylamine in water T=20°C; Inert atmosphereIrradiation;
参考文献
Yamashita, Toshiaki; Matsushita, Shuhei; Nagatomo, Takuya; Yamauchi, Ryosuke; Yasuda, Masahide
Research on Chemical Intermediates, 2013 , vol. 39, # 1 p. 111 - 126
82166-21-0
→
反应条件
5070-59-7
+
590-67-0
1-甲基环己醇
+
1202-74-0
+
583-60-8
2-甲基环己酮
反应条件
polystyrene-supported methyltrioxorhenium; dihydrogen peroxide in tert-butyl alcohol T=40°C; 72 h;
参考文献
Bianchini, Gianluca; Crucianelli, Marcello; Canevali, Carmen; Crestini, Claudia; Morazzoni, Franca; Saladino, Raffaele
Tetrahedron, 2006 , vol. 62, # 52 p. 12326 - 12333
13175-27-4
→
反应条件
5070-59-7
反应条件
(i) Ph3CCl, Py, (ii) Ph3CBF4, CH2Cl2; Multistep reaction;
参考文献
Jung,M.E.; Speltz,L.M.
Journal of the American Chemical Society, 1976 , vol. 98, p. 7882 - 7884
13175-27-4
→
反应条件
19480-04-7
+
5070-59-7
反应条件
palladium diacetate; oxygen; triethylamine in tetrahydrofuran; toluene T=20°C; 15 h; Title compound not separated from byproducts;
参考文献
Schultz, Mitchell J.; Hamilton, Steven S.; Jensen, David R.; Sigman, Matthew S.
Journal of Organic Chemistry, 2005 , vol. 70, # 9 p. 3343 - 3352
13175-27-4
→
反应条件
5070-59-7
+
13175-27-4
反应条件
Rhodococcus ruber DSM 44541 in acetone T=30°C; pH=7.5; 24 h;
参考文献
Edegger, Klaus; Stampfer, Wolfgang; Seisser, Birgit; Faber, Kurt; Mayer, Sandra F.; Oehrlein, Reinhold; Hafner, Andreas; Kroutil, Wolfgang
European Journal of Organic Chemistry, 2006 , # 8 p. 1904 - 1909
110-63-4
1,4-丁二醇
+
67-64-1
丙酮
→
反应条件
5070-59-7
反应条件
di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; triphenylphosphine; potassium hydroxide in toluene T=100°C; 2 h; Inert atmosphere;
参考文献
Iuchi, Yosuke; Hyotanishi, Megumi; Miller, Brittany E.; Maeda, Kensaku; Obora, Yasushi; Ishii, Yasutaka
Journal of Organic Chemistry, 2010 , vol. 75, # 5 p. 1803 - 1806
2046-21-1
6-氧代庚酸甲酯
→
反应条件
5070-59-7
反应条件
1: LiAlH4 3: 51 percent / H2O2; [CH3(n-C8H17)3N]HSO4 / Na2WO4*2H2O / H2O; toluene / 2 h / 90 °C View Scheme
参考文献
Sato, Kazuhiko; Aoki, Masao; Takagi, Junko; Zimmermann, Klaus; Noyori, Ryoji
Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 10 p. 2287 - 2306
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