2,3-二甲基-2,3-环氧丁烷合成路线 （共 115 条）
反应条件
copper-graphimet in gas
T=250°C; other catalysts; other temp.; Product distribution;
参考文献
Molnar, Arpad; Mastalir, Agnes; Bartok, Mihaly
Journal of the Chemical Society, Chemical Communications, 1989 , p. 124 - 126
反应条件
T=369.1 - 459.9°C; P=15 Torr; E(excit); KineticsMechanismThermodynamic data;
参考文献
Flowers, Michael C.; Honeyman, Malcolm R.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1981 , vol. 77, p. 1923 - 1933
反应条件
1: 1.) sodium hydride, butyllithium; 2.) boron trifluoride etherate; 2.) p-toluenesulfonic acid, 4 Angstroem molecular sieves / 1.) hexane, THF, -78 deg C to 0 degC, 2 h; 2.) THF; 3.) benzene, reflux, 1 h
2: 72 percent / KMnO4 / acetic acid / 0.5 h / Ambient temperature
View Scheme
参考文献
Yamaguchi, Masahiko; Hirao, Ichiro
Chemistry Letters, 1985 , p. 337 - 338
参考文献
Henry
Recueil des Travaux Chimiques des Pays-Bas, 1907 , vol. 26, p. 440
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1907 , vol. 144, p. 553 Anm.
Chem. Zentralbl., 1907 , vol. 78, # II p. 584
参考文献
Solar,S. et al.
Monatshefte fuer Chemie, 1973 , vol. 104, p. 220 - 225
