5,5-二甲基-2-苯基-1,3,2-二氧硼杂合成路线 （共 155 条）
反应条件
bis(1,5-cyclooctadiene)nickel (0); cesium fluoride; SIDip*HCl in toluene
T=120°C; Inert atmosphere;
参考文献
Bouffard, Jean; Itami, Kenichiro
Organic Letters, 2009 , vol. 11, # 19 p. 4410 - 4413
反应条件
bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride in toluene
T=80°C; Inert atmosphere;
参考文献
Bouffard, Jean; Itami, Kenichiro
Organic Letters, 2009 , vol. 11, # 19 p. 4410 - 4413
反应条件
1: phenylboronic acid neopentylglycol ester With bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride in 1,4-dioxane; toluene
T=20°C; 0.5 h; Inert atmosphere;
2: 1-methyl-1-pentanol With chlorobenzene in 1,4-dioxane; toluene
T=60 - 80°C; Inert atmosphere;
参考文献
Maekawa, Takehisa; Sekizawa, Hiromi; Itami, Kenichiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7022 - 7026
反应条件
in toluene
T=80°C; 14 h;
参考文献
Maekawa, Takehisa; Sekizawa, Hiromi; Itami, Kenichiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7022 - 7026
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide
T=60°C; Suzuki-Miyauri coupling; 12 h; Inert atmosphere;
参考文献
Yang, Chu-Ting; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3904 - 3907
反应条件
dipotassium hydrogenphosphate; silver carbonate; p-benozquinone; palladium diacetate in tert-butyl alcohol
T=120°C; 3 h;
参考文献
Giri, Ramesh; Maugel, Nathan; Li, Jiao-Jie; Wang, Dong-Hui; Breazzano, Steven P.; Saunders, Lindsey B.; Yu, Jin-Quan
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3510 - 3511
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium tert-butylate; tri-cyclo-hexyl-phosphine in tetrahydrofuran; benzene-d6
T=100°C; 16 h; Inert atmosphere;
参考文献
Daikin Industries; Osaka University; Nagai, Takabumi; Adachi, Kenji; Shibanuma, Takashi; Ogoshi, Sensuke; Ohashi, Masato
Patent: US2013/324757 A1, 2013 ;
Location in patent: Paragraph 0287 ;
反应条件
bis(1,5-cyclooctadiene)nickel (0); caesium carbonate; tri-cyclo-hexyl-phosphine in tetrahydrofuran; benzene-d6
T=100°C; 16 h; Inert atmosphere;
参考文献
Daikin Industries; Osaka University; Nagai, Takabumi; Adachi, Kenji; Shibanuma, Takashi; Ogoshi, Sensuke; Ohashi, Masato
Patent: US2013/324757 A1, 2013 ;
Location in patent: Paragraph 0277-0284 ;
反应条件
bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride in toluene
T=100°C; Inert atmosphere;
参考文献
Bouffard, Jean; Itami, Kenichiro
Organic Letters, 2009 , vol. 11, # 19 p. 4410 - 4413
反应条件
copper diacetate; triethylamine in dichloromethane
T=20°C; 24 h;
参考文献
Chan, Dominic M. T.; Monaco, Kevin L.; Li, Renhua; Bonne, Damien; Clark, Charles G.; Lam, Patrick Y. S.
Tetrahedron Letters, 2003 , vol. 44, # 19 p. 3863 - 3865
