2,3-二甲基-1,3-丁二烯合成路线 （共 777 条）
反应条件
ethanol; nickel T=0°C; Hydrogenation;
参考文献
Lewina et al.
Sb. Statei Obshch. Khim., 1953 , p. 355,359
Chem.Abstr., 1955 , p. 829
反应条件
hydrogen; palladium dichloride in N,N-dimethyl-formamide P=18751.5 Torr; 0.25 h; Ambient temperaturevarious time; Product distribution;
参考文献
Acta Chimica Academiae Scientiarum Hungaricae, , vol. 103, # 1 p. 33 - 42
反应条件
diphenyl diselenide in chloroform-d1 T=20°C; 6 h; Inert atmosphereIrradiation;
参考文献
Mitamura, Takenori; Imanishi, Yoshiaki; Nomoto, Akihiro; Sonoda, Motohiro; Ogawa, Akiya
Bulletin of the Chemical Society of Japan, 2007 , vol. 80, # 12 p. 2443 - 2445
反应条件
in pentane under N2, stirring at room temp, the react. was complete within about 1 h; evapn. (vac.), chromy. on alumina (eluent pentane for the hydrometalated products, and more polar solvents for the dimer), elem. anal., (the org. products identified by GC and NMR);
参考文献
Organometallics, , vol. 8, p. 2225 - 2232
反应条件
in benzene-d6 under N2 for 7-10 min (molar ratio metal hydride:diene = ca. 2:1);; detected by CIDNP studies;;
参考文献
Thomas, Marian J.; Shackleton, Thomas A.; Wright, Steven C.; Gillis, Daniel J.; Colpa, Johannes P.; Baird, Michael C.
Journal of the Chemical Society, Chemical Communications, 1986 , # 4 p. 312 - 314
反应条件
in benzene-d6 under N2 for 7-10 min (molar ratio metal hydride:diene = ca. 2:1);; detected by CIDNP studies;;
参考文献
Thomas, Marian J.; Shackleton, Thomas A.; Wright, Steven C.; Gillis, Daniel J.; Colpa, Johannes P.; Baird, Michael C.
Journal of the Chemical Society, Chemical Communications, 1986 , # 4 p. 312 - 314
反应条件
T=175°C; P=257428 Torr;
参考文献
Adkins; Williams
Journal of Organic Chemistry, 1952 , vol. 17, p. 980,986
参考文献
Dupont; Paquot
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1937 , vol. 205, p. 806
反应条件
T=22°C; Hydrogenation;
参考文献
Gostunskaja et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955 , p. 863,865; engl.Ausg.S.779,780,782
反应条件
carbon monoxide; {Pd([1,10]phenanthroline)2}[BF4]2; triethylamine in tetrahydrofuran T=100°C; P=3750.38 Torr; 6 h; Title compound not separated from byproducts.;
参考文献
Ragaini, Fabio; Cenini, Sergio; Brignoli, Daniela; Gasperini, Michela; Gallo, Emma
Journal of Organic Chemistry, 2003 , vol. 68, # 2 p. 460 - 466
